A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions
文献类型：期刊论文
| 作者 | Dai XC(代兴超); Cui XJ(崔新江) ; Deng YQ(邓友全); Shi F(石峰)
|
| 刊名 | RSC Advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:54页码:43589-43593 |
| ISSN号 | 2046-2069 |
| 通讯作者 | 石峰 |
| 英文摘要 | Here, we show the results of a molecular-defined conjugated ketone catalyzed alcohol amination reaction. Under the optimized reaction conditions, the yields to the desired products reached 98%. The reaction mechanism and kinetic study supposed that carbonyl-hydroxyl groups are the catalytically active sites, and the transfer-hydrogenation reactions progress via the recycling of carbonyl and hydroxyl groups. The catalytic process shows promise as an efficient and economic route for alcohol amination reactions. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000354964600064 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://210.77.64.217/handle/362003/18453]  |
| 专题 | 兰州化学物理研究所_绿色化学研究发展中心 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai XC,Cui XJ,Deng YQ,et al. A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions[J]. RSC Advances,2015,5(54):43589-43593. |
| APA | Dai XC,Cui XJ,Deng YQ,&Shi F.(2015).A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions.RSC Advances,5(54),43589-43593. |
| MLA | Dai XC,et al."A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions".RSC Advances 5.54(2015):43589-43593. |
入库方式： OAI收割
来源：兰州化学物理研究所
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