Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains
文献类型：期刊论文
| 作者 | Wu B(吴彪)1; Huo, Cuirong1; Li SG(李少光)2; Zhao YX(赵艳霞)1; Yang XJ(杨晓娟)1
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| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2015 |
| 卷号 | 641期号:10页码:1786-1791 |
| 关键词 | Oligourea Dihydrogen phosphate Anion clusters Anion coordination NMR spectroscopy UV Vis spectroscopy |
| ISSN号 | 0044-2313 |
| 通讯作者 | 吴彪 |
| 英文摘要 | A series of alkanediyl-spaced bis-bisurea ligands (L2–L4) were synthesized and their anion coordination behavior studied. These ligands form interesting complexes with polymeric and oligomeric dihydrogen phosphate aggregates in the solid state. The ligands L2 and L3 coordinate with H2PO4– anions to form a unique molecular “necklace” with an infinite (H2PO4–)n chain and surrounding ligand molecules. Meanwhile, two different dihydrogen phosphate-water oligomers, (H2PO4)6·(H2O)4 and (H2PO4)4·(H2O)2, were observed in the complexes with the ligands L3 and L4. In addition, solution anion binding properties of the ligands were studied by 1H NMR and UV/Vis spectroscopy. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21271149;21325102) |
| 语种 | 英语 |
| WOS记录号 | WOS:000359294000021 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://210.77.64.217/handle/362003/18557]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu B,Huo, Cuirong,Li SG,et al. Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(10):1786-1791. |
| APA | Wu B,Huo, Cuirong,Li SG,Zhao YX,&Yang XJ.(2015).Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(10),1786-1791. |
| MLA | Wu B,et al."Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.10(2015):1786-1791. |
入库方式： OAI收割
来源：兰州化学物理研究所
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