Palladium-Catalyzed Dearomative Cyclocarbonylation by C—N Bond Activation
文献类型：期刊论文
| 作者 | Yu H(余慧); Zhang GY(张国营) ; Huang HM(黄汉民)
|
| 刊名 | Angewandte Chemie International Edition
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:37页码:10912-10916 |
| 关键词 | CN activation cyclocarbonylation dearomatization palladium quinolizinones |
| ISSN号 | 1433-7851 |
| 通讯作者 | 黄汉民 |
| 英文摘要 | A fundamentally novel approach to bioactive quinolizinones is based on the palladium-catalyzed intramolecular cyclocarbonylation of allylamines. [Pd(Xantphos)I2], which features a very large bite angle, has been found to facilitate the rapid carbonylation of azaarene-substituted allylamines into bioactive quinolizinones in good to excellent yields. This transformation represents the first dearomative carbonylation and is proposed to proceed by palladium-catalyzed C—N bond activation, dearomatization, CO insertion, and a Heck reaction. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Nature Science Foundation of China (21222203;21172226;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000360628500038 |
| 源URL | [http://210.77.64.217/handle/362003/18595]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu H,Zhang GY,Huang HM. Palladium-Catalyzed Dearomative Cyclocarbonylation by C—N Bond Activation[J]. Angewandte Chemie International Edition,2015,54(37):10912-10916. |
| APA | Yu H,Zhang GY,&Huang HM.(2015).Palladium-Catalyzed Dearomative Cyclocarbonylation by C—N Bond Activation.Angewandte Chemie International Edition,54(37),10912-10916. |
| MLA | Yu H,et al."Palladium-Catalyzed Dearomative Cyclocarbonylation by C—N Bond Activation".Angewandte Chemie International Edition 54.37(2015):10912-10916. |
入库方式： OAI收割
来源：兰州化学物理研究所
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