Decarboxylative Alkylcarboxylation of alpha,beta-Unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling
文献类型：期刊论文
| 作者 | Gao B(高宝); Xie YJ(谢银君); Shen ZQ(沈志强) ; Yang L(杨磊); Huang HM(黄汉民); Huang HM(黄汉民)
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| 刊名 | Organic Letters
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:20页码:4968-4971 |
| ISSN号 | 1523-7060 |
| 通讯作者 | 黄汉民 |
| 英文摘要 | A facile and general method for coppercatalyzed decarboxylative alkylcarboxylation of cinnamic acids with dimethyl 2,2'-azobis(2-methylpropionate) has been developed. The scope and versatility of the reaction was demonstrated, and a broad range of substrates bearing electron-donating and -withdrawing groups on the aromatic rings were all compatible with this reaction to provide desired beta,gamma-unsaturated esters in moderate to good yields. Moreover, alpha,beta-unsaturated acids with a carbonyl group on the gamma-position of acrylic acids also smoothly proceeded to furnish the desired products in good yields. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21372231;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000363225000010 |
| 源URL | [http://210.77.64.217/handle/362003/18644]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Huang HM(黄汉民) |
| 作者单位 | Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao B,Xie YJ,Shen ZQ,et al. Decarboxylative Alkylcarboxylation of alpha,beta-Unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling[J]. Organic Letters,2015,17(20):4968-4971. |
| APA | Gao B,Xie YJ,Shen ZQ,Yang L,Huang HM,&黄汉民.(2015).Decarboxylative Alkylcarboxylation of alpha,beta-Unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling.Organic Letters,17(20),4968-4971. |
| MLA | Gao B,et al."Decarboxylative Alkylcarboxylation of alpha,beta-Unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling".Organic Letters 17.20(2015):4968-4971. |
入库方式： OAI收割
来源：兰州化学物理研究所
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