Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality
文献类型：期刊论文
| 作者 | Jiao TF(焦体峰)1,2; Li XuHui1; Zhang QingRui1; Li QiuRong1; Zhou JX(周靖欣)1; Gao FM(高发明)1 |
| 刊名 | SCIENCE CHINA Technological Sciences
 |
| 出版日期 | 2013 |
| 卷号 | 56期号:1页码:20-24 |
| ISSN号 | 1674-7321 |
| 关键词 | interfacial assembly Langmuir-Blodgett film supramolecular chirality Schiff base |
| 通讯作者 | 焦体峰 |
| 英文摘要 | Four achiral Cu(II)-coordinated Schiff bases complexes containing aromatic structures were synthesized and their supramolecular assemblies at the air/water interface were investigated. All the compounds could be spread on water surface although they have no alkyl chains. The Schiff base complex molecules with naphthyl groups tended to form J-aggregate in the Langmuir-Blodgett (LB) films transferred from water surface. By investigation of atomic force microscopy, a multilayer film or three-dimensional structures were observed. It was interesting to note that the LB films of achiral compound Cu-NA with naphthyl segment and without methyl groups transferred from water surface showed chirality. The supramolecular chirality in the present LB films was suggested to be due to a cooperative stereoregular pi-pi stacking of the functional groups in a helical sense. This research work provides a helpful clue for regulating the nanostructures and supramolecular chiral assembly in organized films. |
| 学科主题 | 材料科学与物理化学 |
| 资助信息 | the National Natural Science Foundation of China (Grant Nos. 20903078;21207112);the Natural Science Foundation of Hebei Province (Grant No. B2012203060);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No. CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant No. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant No. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000314375300004 |
| 源URL | [http://210.77.64.217/handle/362003/18175]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.Yanshan Univ, Hebei Key Lab Appl Chem, Sch Environm & Chem Engn, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiao TF,Li XuHui,Zhang QingRui,et al. Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality[J]. SCIENCE CHINA Technological Sciences,2013,56(1):20-24. |
| APA | Jiao TF,Li XuHui,Zhang QingRui,Li QiuRong,Zhou JX,&Gao FM.(2013).Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality.SCIENCE CHINA Technological Sciences,56(1),20-24. |
| MLA | Jiao TF,et al."Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality".SCIENCE CHINA Technological Sciences 56.1(2013):20-24. |
入库方式： OAI收割
来源：兰州化学物理研究所
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