Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives
文献类型:期刊论文
作者 | Jiao TF(焦体峰)1,2; Wang, Renxun1; Zhang, Qingrui1; Yan XB(阎兴斌)2![]() |
刊名 | Current Nanoscience
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出版日期 | 2013 |
卷号 | 9期号:4页码:536-542 |
关键词 | Organogel nanostructure assembly substituent groups imide derivative glutamic acid |
ISSN号 | 1573-4137 |
通讯作者 | 焦体峰 ; Zhang, Qingrui ; 阎兴斌 |
英文摘要 | In this paper new glutamic acid diethyl ester imide derivatives with different alkyl substituent chains were designed and synthesized. Their gelation behaviors in 21 solvents were tested as novel low-molecular-mass organic gelators. It was shown that the length of alkyl substituent chains linked to benzene ring in gelators played a crucial role in the gelation behavior of all compounds in various organic solvents. Longer alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. SEM and AFM observations revealed that the gelator molecules self-assemble into different aggregates from wrinkle, lamella, belt, to fiber with change of solvents. Spectral studies indicated that there existed different H-bond formations and hydrophobic forces, depending on the alkyl substituent chains in molecular skeletons. The present work may give some insight to design and characterize new versatile organogelators and soft materials with special molecular structures. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (Grant Nos. 20903078;21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002);the Top Hundred Talents Program of Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000323746800017 |
源URL | [http://210.77.64.217/handle/362003/18183] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Yanshan Univ, Hebei Key Lab Appl Chem, Sch Environm & Chem Engn, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Jiao TF,Wang, Renxun,Zhang, Qingrui,et al. Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives[J]. Current Nanoscience,2013,9(4):536-542. |
APA | Jiao TF,Wang, Renxun,Zhang, Qingrui,Yan XB,Zhou JX,&Gao FM.(2013).Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives.Current Nanoscience,9(4),536-542. |
MLA | Jiao TF,et al."Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives".Current Nanoscience 9.4(2013):536-542. |
入库方式: OAI收割
来源:兰州化学物理研究所
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