中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives

文献类型:期刊论文

作者Jiao TF(焦体峰)1,2; Wang, Renxun1; Zhang, Qingrui1; Yan XB(阎兴斌)2; Zhou JX(周靖欣)1; Gao FM(高发明)1
刊名Current Nanoscience
出版日期2013
卷号9期号:4页码:536-542
关键词Organogel nanostructure assembly substituent groups imide derivative glutamic acid
ISSN号1573-4137
通讯作者焦体峰 ; Zhang, Qingrui ; 阎兴斌
英文摘要In this paper new glutamic acid diethyl ester imide derivatives with different alkyl substituent chains were designed and synthesized. Their gelation behaviors in 21 solvents were tested as novel low-molecular-mass organic gelators. It was shown that the length of alkyl substituent chains linked to benzene ring in gelators played a crucial role in the gelation behavior of all compounds in various organic solvents. Longer alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. SEM and AFM observations revealed that the gelator molecules self-assemble into different aggregates from wrinkle, lamella, belt, to fiber with change of solvents. Spectral studies indicated that there existed different H-bond formations and hydrophobic forces, depending on the alkyl substituent chains in molecular skeletons. The present work may give some insight to design and characterize new versatile organogelators and soft materials with special molecular structures.
学科主题材料科学与物理化学
收录类别SCI
资助信息the National Natural Science Foundation of China (Grant Nos. 20903078;21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002);the Top Hundred Talents Program of Chinese Academy of Sciences
语种英语
WOS记录号WOS:000323746800017
源URL[http://210.77.64.217/handle/362003/18183]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Yanshan Univ, Hebei Key Lab Appl Chem, Sch Environm & Chem Engn, Qinhuangdao 066004, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Jiao TF,Wang, Renxun,Zhang, Qingrui,et al. Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives[J]. Current Nanoscience,2013,9(4):536-542.
APA Jiao TF,Wang, Renxun,Zhang, Qingrui,Yan XB,Zhou JX,&Gao FM.(2013).Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives.Current Nanoscience,9(4),536-542.
MLA Jiao TF,et al."Nanostructures and Substituent Alkyl Chains Effect on Assembly of Organogels Based on Some Glutamic Acid Diethyl Ester Imide Derivatives".Current Nanoscience 9.4(2013):536-542.

入库方式: OAI收割

来源:兰州化学物理研究所

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