Regulation of substituent groups on morphologies and self-assembly of organogels based on some azobenzene imide derivatives
文献类型:期刊论文
作者 | Jiao TF(焦体峰)1,2; Wang, Yujin1; Zhang, Qingrui1; Zhou JX(周靖欣)1; Gao FM(高发明)1 |
刊名 | Nanoscale Research Letters
![]() |
出版日期 | 2013 |
卷号 | 8 |
关键词 | Organogel Nanostructures Self-assembly Substituent groups Imide derivative Azobenzene |
ISSN号 | 1556-276X |
通讯作者 | 焦体峰 ; Zhang, Qingrui |
英文摘要 | In this paper, new azobenzene imide derivatives with different substituent groups were designed and synthesized. Their gelation behaviors in 21 solvents were tested as novel low-molecular-mass organic gelators. It was shown that the alkyl substituent chains and headgroups of azobenzene residues in gelators played a crucial role in the gelation behavior of all compounds in various organic solvents. More alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. Scanning electron microscopy and atomic force microscopy observations revealed that the gelator molecules self-assemble into different aggregates, from wrinkle, lamella, and belt to fiber with the change of solvents. Spectral studies indicated that there existed different H-bond formations between amide groups and conformations of methyl chains. The present work may give some insight to the design and character of new organogelators and soft materials with special molecular structures. |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (Grant Nos. 20903078;21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
语种 | 英语 |
WOS记录号 | WOS:000317900600001 |
源URL | [http://210.77.64.217/handle/362003/18227] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Yanshan Univ, Hebei Key Lab Appl Chem, Sch Environm & Chem Engn, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Jiao TF,Wang, Yujin,Zhang, Qingrui,et al. Regulation of substituent groups on morphologies and self-assembly of organogels based on some azobenzene imide derivatives[J]. Nanoscale Research Letters,2013,8. |
APA | Jiao TF,Wang, Yujin,Zhang, Qingrui,Zhou JX,&Gao FM.(2013).Regulation of substituent groups on morphologies and self-assembly of organogels based on some azobenzene imide derivatives.Nanoscale Research Letters,8. |
MLA | Jiao TF,et al."Regulation of substituent groups on morphologies and self-assembly of organogels based on some azobenzene imide derivatives".Nanoscale Research Letters 8(2013). |
入库方式: OAI收割
来源:兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。