Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect
文献类型：期刊论文
| 作者 | Jiao TF(焦体峰)1,2; Huang, Qinqin1; Zhang, Qingrui1; Xiao, Debao1; Zhou JX(周靖欣)1; Gao FM(高发明)1 |
| 刊名 | Nanoscale Research Letters
 |
| 出版日期 | 2013 |
| 卷号 | 8 |
| 关键词 | Nanostructure Self-assembly Organogel Luminol derivative Substituent group effect |
| ISSN号 | 1556-276X |
| 通讯作者 | 焦体峰 |
| 英文摘要 | Luminol is considered as an efficient sycpstem in electrochemiluminescence (ECL) measurements for the detection of hydrogen peroxide. In this paper, new luminol imide derivatives with different alkyl substituent chains were designed and synthesized. Their gelation behaviors in 26 solvents were tested as novel low molecular mass organic gelators. It was shown that the length and number of alkyl substituent chains linked to a benzene ring in gelators played a crucial role in the gelation behavior of all compounds in various organic solvents. Longer alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. Scanning electron microscope and atomic force microscope observations revealed that the gelator molecules self-assemble into different micro/nanoscale aggregates from a dot, flower, belt, rod, and lamella to wrinkle with change of solvents. Spectral studies indicated that there existed different H-bond formations and hydrophobic forces, depending on the alkyl substituent chains in molecular skeletons. The present work may give some insight to the design and characteristic of new versatile soft materials and potential ECL biosensors with special molecular structures. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant Nos. 20903078;21073154;21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
| 语种 | 英语 |
| WOS记录号 | WOS:000321100400001 |
| 源URL | [http://210.77.64.217/handle/362003/18236]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiao TF,Huang, Qinqin,Zhang, Qingrui,et al. Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect[J]. Nanoscale Research Letters,2013,8. |
| APA | Jiao TF,Huang, Qinqin,Zhang, Qingrui,Xiao, Debao,Zhou JX,&Gao FM.(2013).Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect.Nanoscale Research Letters,8. |
| MLA | Jiao TF,et al."Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect".Nanoscale Research Letters 8(2013). |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。