中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil

文献类型:期刊论文

作者Li, Zhipeng1,2; Li, Xiufeng1; Zhang, Yawen1; Ren TH(任天辉)1; Zhao, Yidong3; Zeng, Xiangqiong4; van der Heide, E.4
刊名Applied Surface Science
出版日期2014
卷号308页码:91-99
ISSN号0169-4332
关键词Phenylboronic acid ester Heterocyclic compound Hydrolytic stability Anti wear Surface analysis
通讯作者Ren, Tianhui
英文摘要A novel long chain alkyl phenylboronic acid ester containing heterocyclic compound, bis (1(benzothiazol-2-ylthio) propan-2-yl)-4-dodecylphenylboronic acid ester (DBBMT), was synthesized and characterized. The hydrolytic stability of the DBBMT was evaluated and the results show that DBBMT is of outstanding hydrolytic stability compared with normal borate esters, which indicates that the designed molecular structure, by introducing benzene ring to conjugate with the electron-deficient boron and the benzothiazole as a hinder group, is effective on obtaining a hydrolytically stable long chain alkyl phenylboronic acid ester. The tribological properties of DBBMT and ZDDP in mineral base oil were evaluated using a four-ball tribometer, which suggests that the DBBMT possesses comprehensive tribological properties and could be a potential candidate for the replacement of ZDDP. Furthermore, in order to understand the tribological behaviors, the worn surface was analyzed by X-ray photoelectron spectroscopy (XPS) and X-ray absorption near edge structure (XANES) spectroscopy. The results indicate that the elements S, B, O and Fe perform complicated tribochemical reactions to form the compact tribological film composed of B2O3, FeS, Fe3O4 and FeSO4.
学科主题材料科学与物理化学
资助信息the National Natural Science Foundation of China (Grant No. 21272157);the Beijing Synchrotron Radiation Facility (Grant No. SR06033);the open projects of the Key State Lab of Solid Lubrication in Lanzhou of China ((Grant No. 1205)
收录类别SCI
语种英语
WOS记录号WOS:000336599900013
源URL[http://210.77.64.217/handle/362003/18311]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Shanghai Jiao Tong Univ, Key Lab Thin Film & Microfabricat, Minist Educ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Solid Lubricat, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China
4.Univ Twente, Lab Surface Technol & Tribol, NL-7522 NB Enschede, Netherlands
推荐引用方式
GB/T 7714
Li, Zhipeng,Li, Xiufeng,Zhang, Yawen,et al. Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil[J]. Applied Surface Science,2014,308:91-99.
APA Li, Zhipeng.,Li, Xiufeng.,Zhang, Yawen.,Ren TH.,Zhao, Yidong.,...&van der Heide, E..(2014).Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil.Applied Surface Science,308,91-99.
MLA Li, Zhipeng,et al."Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil".Applied Surface Science 308(2014):91-99.

入库方式: OAI收割

来源:兰州化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。