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Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors
文献类型:期刊论文
作者 | Wang RT(王儒涛)1![]() ![]() ![]() |
刊名 | Advanced Functional Materials
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出版日期 | 2015 |
卷号 | 25期号:15页码:2270-2278 |
ISSN号 | 1616-301X |
通讯作者 | 阎兴斌 |
英文摘要 | Li-ion hybrid capacitors (LIHCs), consisting of an energy-type redox anode and a power-type double-layer cathode, are attracting significant attention due to the good combination with the advantages of conventional Li-ion batteries and supercapacitors. However, most anodes are battery-like materials with the sluggish kinetics of Li-ion storage, which seriously restrict the energy storage of LIHCs at the high charge/discharge rates. Herein, vanadium nitride (VN) nanowire is demonstated to have obvious pseudocapacitive characteristic of Li-ion storage and can get further gains in energy storage through a 3D porous architecture with the assistance of conductive reduced graphene oxide (RGO). The as-prepared 3D VN–RGO composite exhibits the large Li-ion storage capacity and fast charge/discharge rate within a wide working widow from 0.01–3 V (vs Li/Li+), which could potentially boost the operating potential and the energy and power densities of LIHCs. By employing such 3D VN–RGO composite and porous carbon nanorods with a high surface area of 3343 m2 g−1 as the anode and cathode, respectively, a novel LIHCs is fabricated with an ultrahigh energy density of 162 Wh kg−1 at 200 W kg−1, which also remains 64 Wh kg−1 even at a high power density of 10 kW kg−1. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | the National Defense Basic Research Program of China;the National Nature Science Foundations of China (Grant No. 21203223) |
语种 | 英语 |
WOS记录号 | WOS:000353057600008 |
源URL | [http://210.77.64.217/handle/362003/18407] ![]() |
专题 | 兰州化学物理研究所_清洁能源化学与材料实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Wang RT,Lang JW,Zhang P,et al. Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors[J]. Advanced Functional Materials,2015,25(15):2270-2278. |
APA | Wang RT,Lang JW,Zhang P,Lin, Zongyuan,&Yan XB.(2015).Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors.Advanced Functional Materials,25(15),2270-2278. |
MLA | Wang RT,et al."Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors".Advanced Functional Materials 25.15(2015):2270-2278. |
入库方式: OAI收割
来源:兰州化学物理研究所
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