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Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors

文献类型:期刊论文

作者Wang RT(王儒涛)1; Lang JW(郎俊伟)1,2; Zhang P(张鹏)1; Lin, Zongyuan1; Yan XB(阎兴斌)1,2
刊名Advanced Functional Materials
出版日期2015
卷号25期号:15页码:2270-2278
ISSN号1616-301X
通讯作者阎兴斌
英文摘要
Li-ion hybrid capacitors (LIHCs), consisting of an energy-type redox anode and a power-type double-layer cathode, are attracting significant attention due to the good combination with the advantages of conventional Li-ion batteries and supercapacitors. However, most anodes are battery-like materials with the sluggish kinetics of Li-ion storage, which seriously restrict the energy storage of LIHCs at the high charge/discharge rates. Herein, vanadium nitride (VN) nanowire is demonstated to have obvious pseudocapacitive characteristic of Li-ion storage and can get further gains in energy storage through a 3D porous architecture with the assistance of conductive reduced graphene oxide (RGO). The as-prepared 3D VN–RGO composite exhibits the large Li-ion storage capacity and fast charge/discharge rate within a wide working widow from 0.01–3 V (vs Li/Li+), which could potentially boost the operating potential and the energy and power densities of LIHCs. By employing such 3D VN–RGO composite and porous carbon nanorods with a high surface area of 3343 m2 g−1 as the anode and cathode, respectively, a novel LIHCs is fabricated with an ultrahigh energy density of 162 Wh kg−1 at 200 W kg−1, which also remains 64 Wh kg−1 even at a high power density of 10 kW kg−1.
学科主题材料科学与物理化学
收录类别SCI
资助信息the National Defense Basic Research Program of China;the National Nature Science Foundations of China (Grant No. 21203223)
语种英语
WOS记录号WOS:000353057600008
源URL[http://210.77.64.217/handle/362003/18407]  
专题兰州化学物理研究所_清洁能源化学与材料实验室
兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Wang RT,Lang JW,Zhang P,et al. Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors[J]. Advanced Functional Materials,2015,25(15):2270-2278.
APA Wang RT,Lang JW,Zhang P,Lin, Zongyuan,&Yan XB.(2015).Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors.Advanced Functional Materials,25(15),2270-2278.
MLA Wang RT,et al."Fast and Large Lithium Storage in 3D Porous VN Nanowires-Graphene Composite as a Superior Anode Toward High-Performance Hybrid Supercapacitors".Advanced Functional Materials 25.15(2015):2270-2278.

入库方式: OAI收割

来源:兰州化学物理研究所

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