In this work, novel zinc–graphene oxide (Zn–GO) composite coatings were successfully prepared by pulse electrodeposition in choline chloride (ChCl)/urea based deep eutectic solvent (DES). The GO sheets exhibited excellent dispersion stability in ChCl:2urea DES without stabilizing additives and were uniformly deposited in the Zn matrix. The surface morphology and textured structure of the Zn–GO composite coatings were quite different from those of pure Zn coating, owing to the effects of GO on the electrochemical deposition behavior of Zn(II). The Zn–GO composite coatings showed higher stability and better corrosion resistance than the pure Zn coating and the corrosion resistance of Zn–GO composite coatings increased with the increase of the GO concentration.