Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts
文献类型：期刊论文
| 作者 | Wang PX(王培学)1,2 ; Liu SM(刘士民)1; Zhou F(周锋)1,2; Yang BQ(杨本群)1,2; Alshammari, Ahmad S.3; Deng YQ(邓友全)1
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| 刊名 | RSC Advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:103页码:84621-84626 |
| ISSN号 | 2046-2069 |
| 通讯作者 | 邓友全 |
| 英文摘要 | Square-shaped Zn/Ti oxides were prepared by a co-precipitation method and used for the synthesis of diphenyl carbonate (DPC) via transesterification of dibutyl carbonate (DBC) with phenol. The results showed that a 51% yield of butyl phenyl carbonate (BPC) and 13% yield of DPC could be achieved at 205 degrees C in the presence of 3ZnTi-400 (Zn : Ti molar ratio 3 : 1). Moreover, it is found that 3ZnTi-400 was also an active catalyst for the disproportionation of BPC to DPC, and 80% conversion of BPC was obtained at 190 degrees C. The prepared catalysts could be reused for three runs of the transesterification without noticeable deactivation. The catalysts were characterized by XRD, SEM, XPS, and TPD with the aim of establishing the relationship between catalytic performance and structure. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000362851000035 |
| 源URL | [http://210.77.64.217/handle/362003/18756]  |
| 专题 | 兰州化学物理研究所_绿色化学研究发展中心 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.King Abdulaziz City Sci & Technol, Natl Nanotechnol Res Ctr, Riyadh 11442, Saudi Arabia |
| 推荐引用方式 GB/T 7714 | Wang PX,Liu SM,Zhou F,et al. Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts[J]. RSC Advances,2015,5(103):84621-84626. |
| APA | Wang PX,Liu SM,Zhou F,Yang BQ,Alshammari, Ahmad S.,&Deng YQ.(2015).Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts.RSC Advances,5(103),84621-84626. |
| MLA | Wang PX,et al."Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts".RSC Advances 5.103(2015):84621-84626. |
入库方式： OAI收割
来源：兰州化学物理研究所
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