Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon
文献类型：期刊论文
| 作者 | Li, YZ; Gong, Y; Zhou, XJ; Su, J; Li, J; Zhou, MF |
| 刊名 | JOURNAL OF MOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2015 |
| 卷号 | 310页码:50—56 |
| 关键词 | LANTHANIDE METAL ATOMS GAS-PHASE REACTIONS ROOM-TEMPERATURE KINETICS MATRIX-ISOLATION REACTION-PRODUCTS GROUND-STATE LA-LU DENSITY CATIONS SPECTRA |
| 英文摘要 | Reactions of cerium metal atoms with methanol are investigated using matrix isolation infrared absorption spectroscopy and density functional theoretical calculations. Upon reaction of the ground state cerium metal atoms with methanol, the insertion intermediate CH3OCeH is formed spontaneously on annealing in solid argon. Further sample annealing allows the reaction of CH3OCeH with another methanol molecule to form H-2 and Ce(OCH3)(2). The divalent Ce(OCH3)(2) molecule can further isomerize to the more stable tetravalent CH3OCe(O)CH3 isomer under UV-visible irradiation. The product species are identified via isotopic substitutions and vibrational frequency calculations. (C) 2014 Elsevier Inc. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24478]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Li, YZ,Gong, Y,Zhou, XJ,et al. Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2015,310:50—56. |
| APA | Li, YZ,Gong, Y,Zhou, XJ,Su, J,Li, J,&Zhou, MF.(2015).Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon.JOURNAL OF MOLECULAR SPECTROSCOPY,310,50—56. |
| MLA | Li, YZ,et al."Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon".JOURNAL OF MOLECULAR SPECTROSCOPY 310(2015):50—56. |
入库方式： OAI收割
来源：上海应用物理研究所
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