Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF4] and Acetonitrile
文献类型：期刊论文
| 作者 | Zhu, GL; Wang, Y; Zhang, LW; Liu, YC; Wu, GZ |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2015 |
| 卷号 | 31期号:3页码:419—424 |
| 关键词 | PHOTOINDUCED ELECTRON-TRANSFER LASER PHOTOLYSIS AQUEOUS-SOLUTION TRIPLET-STATE SPECTROSCOPY ORGANIZATION DYNAMICS BEHAVIOR SOLVENTS |
| 英文摘要 | Photochemical reactions of duroquinone (DQ) in solutions consisting of mixtures of the ionic liquid N-butylpyridinium tetrafluoroborate ([BPy][BF4]) and acetonitrile (MeCN) were studied using the 355 nm laser flash photolysis technique. Increasing the ratio of [BPy][BF4] had no obvious impact on the absorption peak of the triplet excited state of DQ ((3)Da), which followed monoexponential kinetics in the N-2-saturated solution. However, increasing the ratio of [BPy] [BF4] did affect the photoinduced electron transfer process from triethylamine to (3)DQ in the mixture by decreasing the reaction rate and the quantum yield of the transient radical. The results highlight the ability to tune the efficiency and the rate of the photoinduced electron transfer by changing the proportion of [BPy][BF4] in the mixture. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24530]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhu, GL,Wang, Y,Zhang, LW,et al. Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF4] and Acetonitrile[J]. ACTA PHYSICO-CHIMICA SINICA,2015,31(3):419—424. |
| APA | Zhu, GL,Wang, Y,Zhang, LW,Liu, YC,&Wu, GZ.(2015).Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF4] and Acetonitrile.ACTA PHYSICO-CHIMICA SINICA,31(3),419—424. |
| MLA | Zhu, GL,et al."Photochemical Reaction Kinetics of Duroquinone in a Mixture of Ionic Liquid [BPy][BF4] and Acetonitrile".ACTA PHYSICO-CHIMICA SINICA 31.3(2015):419—424. |
入库方式： OAI收割
来源：上海应用物理研究所
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