Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands
文献类型：期刊论文
| 作者 | Zhang, N; Sun, YJ; Yang, H; Zhang, JY; Gao, EQ |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2015 |
| 卷号 | 428页码:37—43 |
| 关键词 | METAL-ORGANIC FRAMEWORKS COMPLEXES 2 CONSTRUCTION TEMPERATURE 1D 2'-DINITROBIPHENYL-4 4'-DICARBOXYLATE |
| 英文摘要 | Three Ni(II-)based metal-organic frameworks (MOFs) were synthesized from the nitro-functionalized dicarboxylate ligand 2,2'-dinitro-biphenyl-4,4'-dicarboxylate (H(2)dnpdc) and different N-donor bridging ligands. X-ray analyses revealed that all compounds exhibit 3D architectures. Compound 1, {Ni(dnpdc)(bipy)}(n), exhibits 3D framework in which the 2D Ni(dnpdc) sheets are pillared by bipy, with a new (4,6)-connected self-penetrated net topology. In compound 2, {[Ni-3(dnpdc)(3)(bipy)(3)(H2O)(2)]center dot(H2O)(2)}(n), the binuclear Ni-2(COO)(2) units and mononuclear units are interlinked by the dnpdc and bipy ligands into 3D framework, which displays a rare 3-fold interpenetrated (4,6)-connected net topology. Compound 3, {Ni(dnpdc)(bpee)center dot H2O}(n), displays a 6-fold interpenetrated diamond net based on the mononuclear Ni-II unit. The magnetic studies of 1 reveal that the double carboxylate bridges in the nonplanar syn-skew conformation mediate ferromagnetic interactions between the NiII ions. (C) 2015 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24571]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhang, N,Sun, YJ,Yang, H,et al. Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands[J]. INORGANICA CHIMICA ACTA,2015,428:37—43. |
| APA | Zhang, N,Sun, YJ,Yang, H,Zhang, JY,&Gao, EQ.(2015).Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands.INORGANICA CHIMICA ACTA,428,37—43. |
| MLA | Zhang, N,et al."Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands".INORGANICA CHIMICA ACTA 428(2015):37—43. |
入库方式： OAI收割
来源：上海应用物理研究所
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