Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions
文献类型：期刊论文
| 作者 | Wang, YL; Liu, ZY; Li, YX; Bai, ZL; Liu, W; Wang, YX; Xu, XM; Xiao, CL; Sheng, DP; Juan, DW |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2015 |
| 卷号 | 137期号:19页码:6144—6147 |
| 关键词 | CATION-CATION INTERACTIONS METAL-ORGANIC FRAMEWORKS CRYSTAL-STRUCTURES ION COORDINATION WASTE FORMS COMPLEXES ACTINIDES PEROXIDE CLUSTERS SYSTEM |
| 英文摘要 | Searching for new chemically durable and radiation-resistant absorbent materials for actinides and their fission products generated in the nuclear fuel cycle remain highly desirable, for both waste management and contamination remediation. Here we present a rare case of 3D utanyl organic framework material built through polycatenating of three sets of gtaphene-like layers, which exhibits significant umbellate distortions in the uranyl equatorial planes studied thoroughly by linear transit calculations. This unique structural arrangement leads to high beta and gamma radiation-resistance and chemical stability in aqueous solutions within a wide pH range from 3 to 12. Being equipped with the highest surface area among all actinide compounds known to date and completely exchangeable [(CH3)(2)NH2](+) cations in the structure, this material is able to selectively remove cesium from aqueous solutions while retaining the polycatenated framework structure. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24617]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, YL,Liu, ZY,Li, YX,et al. Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(19):6144—6147. |
| APA | Wang, YL.,Liu, ZY.,Li, YX.,Bai, ZL.,Liu, W.,...&Wang, S.(2015).Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(19),6144—6147. |
| MLA | Wang, YL,et al."Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.19(2015):6144—6147. |
入库方式： OAI收割
来源：上海应用物理研究所
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