Understanding the blue color in antique mosaic mirrored glass from the Temple of the Emerald Buddha, Thailand
文献类型：期刊论文
| 作者 | Klysubun, W; Hauzenberger, CA; Ravel, B; Klysubun, P; Huang, YY; Wongtepa, W; Sombunchoo, P |
| 刊名 | X-RAY SPECTROMETRY
 |
| 出版日期 | 2015 |
| 卷号 | 44期号:3页码:116—123 |
| 关键词 | RAY-ABSORPTION SPECTROSCOPY SYNCHROTRON-RADIATION SILICATE-GLASSES IRON YELLOW ORIGIN COPPER STATE IONS RED |
| 英文摘要 | Two samples of the blue glass produced in the middle 19th century from the Temple of the Emerald Buddha in Bangkok, Thailand, were studied in order to understand the origin of its blue color. The oxide components and trace elements are quantitatively determined by scanning electron microscopy coupled with energy-dispersive and wavelength-dispersive spectrometry and laser ablation inductively coupled plasma mass spectroscopy techniques. The results identify the glass type as soda-lime-silica glass with high lead content. The 3d transition elements detected include iron, manganese, cobalt, and copper. Combined analyses of X-ray absorption near edge structures and optical absorbance lead to a conclusion that the antique glass is primarily colored in blue by the divalent cobalt with additional yellow coloration as a result of the trivalent iron. The tetrahedral coordination geometry of these two species was deduced from the XANES pre-edge intensity and the optical absorption bands of their d-d transitions. The redox ratios of Fe2+/Fe3+, Mn2+/Mn3+, and Cu1+/Cu2+ in the original blue glass and the reference glasses were determined by the K-edge XANES analysis. The blue color of the antique glass can be reproduced in a laboratory glass on the basis of composition and melting conditions. Copyright (c) 2015 John Wiley & Sons, Ltd. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24618]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Klysubun, W,Hauzenberger, CA,Ravel, B,et al. Understanding the blue color in antique mosaic mirrored glass from the Temple of the Emerald Buddha, Thailand[J]. X-RAY SPECTROMETRY,2015,44(3):116—123. |
| APA | Klysubun, W.,Hauzenberger, CA.,Ravel, B.,Klysubun, P.,Huang, YY.,...&Sombunchoo, P.(2015).Understanding the blue color in antique mosaic mirrored glass from the Temple of the Emerald Buddha, Thailand.X-RAY SPECTROMETRY,44(3),116—123. |
| MLA | Klysubun, W,et al."Understanding the blue color in antique mosaic mirrored glass from the Temple of the Emerald Buddha, Thailand".X-RAY SPECTROMETRY 44.3(2015):116—123. |
入库方式： OAI收割
来源：上海应用物理研究所
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