Use of square wave voltammeter for online monitoring of O2- concentration in molten fluorides at 600 degrees C
文献类型：期刊论文
| 作者 | Shen, M; Peng, H; Ge, M ; Zuo, Y; Xie, LD
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| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 748页码:34—39 |
| 关键词 | HYDROGEN FLUORIDE REDUCTION IONS |
| 英文摘要 | The total concentrations of oxide and oxygenated anions in FLINAK melts were detected by using LECO oxygen detector and ion chromatography, respectively. The practical O2- concentration was measured by subtracting the concentration of oxide in oxygenated anions from the total concentration of oxide. Square wave voltammeter (SWV) was then applied to determine the electrochemical behavior of O2- in FLINAK melts at 600 degrees C, which revealed that the process of oxidation from O2- to oxygen was controlled by diffusion. The quantitative relation between O2- concentration and peak current density was also established. The solubility product of ZrO2 was measured as (5.532-6.327) x 10(-7) mol(2)/kg(3) through SWV. (C) 2015 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24621]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Shen, M,Peng, H,Ge, M,et al. Use of square wave voltammeter for online monitoring of O2- concentration in molten fluorides at 600 degrees C[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2015,748:34—39. |
| APA | Shen, M,Peng, H,Ge, M,Zuo, Y,&Xie, LD.(2015).Use of square wave voltammeter for online monitoring of O2- concentration in molten fluorides at 600 degrees C.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,748,34—39. |
| MLA | Shen, M,et al."Use of square wave voltammeter for online monitoring of O2- concentration in molten fluorides at 600 degrees C".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 748(2015):34—39. |
入库方式： OAI收割
来源：上海应用物理研究所
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