ZnO-dotted porous ZnS cluster microspheres for high efficient, Pt-free photocatalytic hydrogen evolution
文献类型：期刊论文
| 作者 | Wu, AP; Jing, LQ; Wang, JQ; Qu, Y; Xie, Y; Jiang, BJ; Tian, CG; Fu, HG |
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2015 |
| 卷号 | 5页码:— |
| 关键词 | VISIBLE-LIGHT IRRADIATION H-2 PRODUCTION TIO2 CATALYSIS NANOPARTICLES NANOCRYSTALS GENERATION MOS2 CDS NANOARCHITECTURES |
| 英文摘要 | The Pt-free photocatalytic hydrogen evolution (PHE) has been the focus in the photocatalysis field. Here, the ZnO-dotted porous ZnS cluster microsphere (PCMS) is designed for high efficient, Pt-free PHE. The PCMS is designed through an easy "controlling competitive reaction'' strategy by selecting the thiourea as S2- source and Zn(Ac)(2)center dot 2H(2)O as Zn source in ethylene glycol medium. Under suitable conditions, one of the PCMS, named PCMS-1, with high SBET specific area of 194 m(2)g(-1), microsphere size of 100 nm and grain size of 3 nm can be obtained. The formation of PCMS is verified by TEM, XAES, XPS, Raman and IR methods. Importantly, a series of the experiments and theoretical calculation demonstrate that the dotting of ZnO not only makes the photo-generated electrons/hole separate efficiently, but also results in the formation of the active catalytic sites for PHE. As a result, the PCMS-1 shows the promising activity up to 367 mu mol h(-1) under Pt-free condition. The PHE activity has no obvious change after addition 1 wt.% Pt, implying the presence of active catalytic sites for hydrogen evolution in the PCMS-1. The easy synthesis process, low preparation cost of the PCMS makes their large potential for Pt-free PHE. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-12-24 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24625]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wu, AP,Jing, LQ,Wang, JQ,et al. ZnO-dotted porous ZnS cluster microspheres for high efficient, Pt-free photocatalytic hydrogen evolution[J]. SCIENTIFIC REPORTS,2015,5:—. |
| APA | Wu, AP.,Jing, LQ.,Wang, JQ.,Qu, Y.,Xie, Y.,...&Fu, HG.(2015).ZnO-dotted porous ZnS cluster microspheres for high efficient, Pt-free photocatalytic hydrogen evolution.SCIENTIFIC REPORTS,5,—. |
| MLA | Wu, AP,et al."ZnO-dotted porous ZnS cluster microspheres for high efficient, Pt-free photocatalytic hydrogen evolution".SCIENTIFIC REPORTS 5(2015):—. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。