Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst
文献类型:期刊论文
作者 | Ayodele, Olubunmi O.1,2,3; Dawodu, Folasegun A.2; Yan, Dongxia1; Lu, Xingmei1; Xin, Jiayu1; Zhang, Suojiang1 |
刊名 | RENEWABLE ENERGY
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出版日期 | 2016-02-01 |
卷号 | 86期号:FEB页码:943-948 |
关键词 | Angelica lactone Levulinic acid Di/trimerization Biogasoline Bifunctional catalyst |
ISSN号 | 0960-1481 |
英文摘要 | Fractionation of biomass to furan derivatives followed by hydrodeoxygenation could provide an efficient route for bioalkanes production. A simple catalytic process to obtain fuels rich in alkanes with 8-12 carbons via hydrodeoxygenation of biomass-derived angelica lactone dimers/trimers was investigated. Dimers and trimers obtained by C-C coupling of alpha- and beta-angelica lactones were hydrodeoxygenated over a bifunctional catalyst, nickel supported on silica-alumina (Ni/SiO2-Al2O3). Reaction conditions such as hydrogen pressure, temperature and time were considered and it was observed that changes in reaction conditions had significant effect on product distributions. Effective conversion of di/trimers of angelica lactone was achieved over Ni/SiO2-Al2O3 with highly branched alkanes and aromatics being selectively produced. The hydrogenated products which are similar in composition to fossil-derived gasoline could further encourage research into more efficient processes to produce bioalkanes on an industrial scale. (C) 2015 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Energy & Fuels |
研究领域[WOS] | Energy & Fuels |
关键词[WOS] | TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; BIOMASS ; LIQUID ; CONVERSION ; ALKANES ; HYDROCARBONS ; CHEMICALS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000364248300093 |
源URL | [http://ir.ipe.ac.cn/handle/122111/19772] ![]() |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Ibadan, Dept Chem Ind, Ibadan, Oyo State, Nigeria 3.Forestry Res Inst Nigeria, Dept Forest Prod Dev & Utilizat, Ibadan, Oyo State, Nigeria |
推荐引用方式 GB/T 7714 | Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,et al. Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst[J]. RENEWABLE ENERGY,2016,86(FEB):943-948. |
APA | Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2016).Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst.RENEWABLE ENERGY,86(FEB),943-948. |
MLA | Ayodele, Olubunmi O.,et al."Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst".RENEWABLE ENERGY 86.FEB(2016):943-948. |
入库方式: OAI收割
来源:过程工程研究所
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