Imidazole tailored deep eutectic solvents for CO2 capture enhanced by hydrogen bonds
文献类型：期刊论文
| 作者 | Cao, Lingdi1,2,3; Huang, Junhua3,4; Zhang, Xiangping1; Zhang, Suojiang1; Gao, Jubao1; Zeng, Shaojuan1,2 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:41页码:27306-27316 |
| ISSN号 | 1463-9076 |
| 英文摘要 | Deep eutectic solvents (DESs) have emerged as promising alternative candidates for CO2 capture in recent years. In this work, several novel DESs were firstly prepared to enhance CO2 absorption. Structural and physical properties of DESs were investigated, as well as their absorption performance of CO2. A distinct depression in the melting point up to 80 K of DESs was observed compared with that of BMIMCl. The observed red shifts of the C2H group in an imidazolium ring and its chemical shifts downfield in NMR spectra are indicative of a hydrogen bond interaction between BMIMCl and MEA. In particular, CO2 uptake in MEA: ILs (4:1) at room temperature and atmospheric pressure is up to 21.4 wt%, which is higher than that of 30 wt% MEA (13%). A hydrogen bond related mechanism was proposed in which ILs act as a medium to improve CO2 uptake through hydrogen bonds. Finally, the firstly reported overall heat of CO2 absorption is slightly higher than that of 30 wt% MEA, implying that the hydrogen bonds of DESs contribute to the overall heat of CO2 absorption. This study reveals that the heat of CO2 absorption can be tailored by the proper molar ratio of MEA and ILs. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | TEMPERATURE IONIC LIQUIDS ; CARBON-DIOXIDE CAPTURE ; PRESSURE PHASE-BEHAVIOR ; EFFICIENT SO2 CAPTURE ; CHOLINE-CHLORIDE ; LOW-VISCOSITY ; MODERATE PRESSURES ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; HOLE THEORY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000363193800009 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/19744]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 3.CSIRO Energy Technol, Clayton, Vic 3169, Australia 4.Monash Univ, Sch Chem, Clayton, Vic 3800, Australia |
| 推荐引用方式 GB/T 7714 | Cao, Lingdi,Huang, Junhua,Zhang, Xiangping,et al. Imidazole tailored deep eutectic solvents for CO2 capture enhanced by hydrogen bonds[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2015,17(41):27306-27316. |
| APA | Cao, Lingdi,Huang, Junhua,Zhang, Xiangping,Zhang, Suojiang,Gao, Jubao,&Zeng, Shaojuan.(2015).Imidazole tailored deep eutectic solvents for CO2 capture enhanced by hydrogen bonds.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,17(41),27306-27316. |
| MLA | Cao, Lingdi,et al."Imidazole tailored deep eutectic solvents for CO2 capture enhanced by hydrogen bonds".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 17.41(2015):27306-27316. |
入库方式： OAI收割
来源：过程工程研究所
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