Vapor-Liquid Equilibrium Data for Binary Systems of N,N-Dimethylacetamide with Cyclohexene, Cyclohexane, and Benzene Separately at Atmospheric Pressure
文献类型:期刊论文
作者 | Mi, Wanliang1; Tong, Ruixin1; Hua, Chao2; Yue, Kai1; Jia, Debiao2; Lu, Ping2; Bai, Fang2 |
刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
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出版日期 | 2015-11-01 |
卷号 | 60期号:11页码:3063-3068 |
ISSN号 | 0021-9568 |
英文摘要 | The reaction for hydrogenation of benzene has been paid much attention as the demand for synthesis of nylon rapid developa. Usually, byproducts of cyclohexane and unreacted benzene unavoidably exist in the production of cyclohexene through the hydrogenation of benzene route. To obtain cyclohexene with high purity, extractive distillation is used to separate cyclohexene mixture. However, the process simulation for extractive distillation is necessary for industry design and production, which requires the relevant vapor liquid equilibrium (VLE) data to simulate accurately. The VLE data for the binary systems of extractant N,N-dimethylacetamide (DMAC) with cyclohexene, cyclohexane, and benzene at atmospheric pressure was measured using a PH-I-type VLE kettle. In addition, a thermodynamic consistency check has been done on the obtained data, indicating that the experimental data satisfy the examination of the thermodynamic consistencies. Moreover, the results are significantly close when NRTL and Wilson equations are used to correlate with data. The maximum deviation for the average vapor composition and the average temperature composition are 0.0095 K and 1.12 K, respectively, which is satisfactory for the separation engineering design requirement. The results could provide basic data for practical application. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical |
研究领域[WOS] | Thermodynamics ; Chemistry ; Engineering |
关键词[WOS] | MIXTURES ; KPA |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000364796600001 |
源URL | [http://ir.ipe.ac.cn/handle/122111/19839] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Univ Sci & Technol Beijing, Sch Mech Engn, Dept Thermal Sci & Energy Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Mi, Wanliang,Tong, Ruixin,Hua, Chao,et al. Vapor-Liquid Equilibrium Data for Binary Systems of N,N-Dimethylacetamide with Cyclohexene, Cyclohexane, and Benzene Separately at Atmospheric Pressure[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2015,60(11):3063-3068. |
APA | Mi, Wanliang.,Tong, Ruixin.,Hua, Chao.,Yue, Kai.,Jia, Debiao.,...&Bai, Fang.(2015).Vapor-Liquid Equilibrium Data for Binary Systems of N,N-Dimethylacetamide with Cyclohexene, Cyclohexane, and Benzene Separately at Atmospheric Pressure.JOURNAL OF CHEMICAL AND ENGINEERING DATA,60(11),3063-3068. |
MLA | Mi, Wanliang,et al."Vapor-Liquid Equilibrium Data for Binary Systems of N,N-Dimethylacetamide with Cyclohexene, Cyclohexane, and Benzene Separately at Atmospheric Pressure".JOURNAL OF CHEMICAL AND ENGINEERING DATA 60.11(2015):3063-3068. |
入库方式: OAI收割
来源:过程工程研究所
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