中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of aging condition on species transformation in polymeric Al salt coagulants

文献类型:会议论文

作者Feng, Chenghong; Ge, Xiaopeng; Wang, Dongsheng; Tang, Hongxiao
出版日期2011
会议名称6th International Conference on Interfaces Against Pollution (IAP 2010)
会议日期MAY 16-19, 2010
会议地点Beijing, PEOPLES R CHINA
关键词Aging condition Species transformation Hexameric ring structure Morphology
英文摘要Effect of aging time and aging temperature on the transformation process of Al species in hydroxyl Al solutions were analyzed by Ferron assay and Al-27 NMR spectroscopy with the help of analysis results of pH, turbidity and morphology of samples. Owing to the high chemical energy provided by elevated temperature, aging temperature exerted greater effect on the transformation of polymers than aging time. Elevation of aging temperature enhanced the transformation rate of various Al species in solution. Polymerization or hydrolysis of monomers in solution was not detected under various aging conditions. Polymeric Al species with non-Keggin structure (e.g., hexameric ring structure) were less stable than Keggin-Al-13. The decomposition of Al-13 only occurred at higher aging temperature. The coexistence of oligomers affected the transformation of Al-13. Morphology and species composition of colloidal Al species transformed from Al-13 were different from those from polymeric Al species with non-Keggin structure. Changes in pH, turbidity and morphology of samples agreed well with the distribution of Al species obtained by Ferron assay and Al-27 NMR spectroscopy. (C) 2010 Elsevier B.V. All rights reserved.
ISBN号0927-7757
WOS记录号WOS:000289920200011
源URL[http://ir.rcees.ac.cn/handle/311016/24627]  
专题生态环境研究中心_环境水质学国家重点实验室
推荐引用方式
GB/T 7714
Feng, Chenghong,Ge, Xiaopeng,Wang, Dongsheng,et al. Effect of aging condition on species transformation in polymeric Al salt coagulants[C]. 见:6th International Conference on Interfaces Against Pollution (IAP 2010). Beijing, PEOPLES R CHINA. MAY 16-19, 2010.

入库方式: OAI收割

来源:生态环境研究中心

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