A nanocrystalline zirconium carbide coating as a functional corrosion-resistant barrier for polymer electrolyte membrane fuel cell application
文献类型：期刊论文
| 作者 | Xu J; Li ZY(李正阳) ; Xu S; Munroe P; Xie ZH
|
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2015-11-30 |
| 卷号 | 297页码:359-369 |
| 通讯作者邮箱 | xujiang73@nuaa.edu.cn |
| 关键词 | Polymer electrolyte membrane fuel cell (PEMFC) Bipolar plate Titanium alloy ZrC coating Corrosion resistance |
| ISSN号 | 0378-7753 |
| 产权排序 | [Xu, Jiang] Nanjing Univ Aeronaut & Astronaut, Dept Mat Sci & Engn, Nanjing 210016, Jiangsu, Peoples R China; [Xu, Jiang; Xie, Zong-Han] Wuhan Inst Technol, Sch Mech & Elect Engn, Wuhan 430073, Peoples R China; [Li, ZhengYang] Chinese Acad Sci, Inst Mech, Beijing 100190, Peoples R China; [Xu, Song; Munroe, Paul] Univ New S Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia; [Xie, Zong-Han] Univ Adelaide, Sch Mech Engn, Adelaide, SA 5005, Australia |
| 通讯作者 | Xu, J (reprint author), Nanjing Univ Aeronaut & Astronaut, Dept Mat Sci & Engn, 29 Yudao St, Nanjing 210016, Jiangsu, Peoples R China. |
| 中文摘要 | A ZrC nanocrystalline coating is engineered onto a Ti-6Al-4V substrate using a double cathode glow discharge technique in order to improve the corrosion resistance and long-term stability of this alloy. The new coating exhibits an extremely dense, homogeneous microstructure composed of equiaxed grains with an average grain size of similar to 12 nm and is well adhered on the surface of the substrate. The corrosion behaviour of the coating is systematically investigated using various electrochemical methods, including potentiodynamic, potentiostatic polarizations and electrochemical impedance spectroscopy (EIS), in a simulated polymer electrolyte membrane fuel cell (PEMFC) operating circumstances under different temperatures. The results show that with rising temperature, the corrosion potential (E-corr) decreases and the corrosion current density (i(corr)) of the ZrC coated specimen increases, indicating that the corrosion resistance decreased with increasing temperature. However, at a given temperature, the ZrC-coated Ti-6Al-4V alloy has a higher E-corr and lower icorr as compared to the bare substrate. The results of EIS measurements show that the values of the resistance for the ZrC coated Ti-6Al-4V alloy are three orders of magnitude larger than those of Ti-6Al-4V in the simulated PEMFC environment. (C) 2015 Elsevier B.V. All rights reserved. |
| 分类号 | 一类 |
| 类目[WOS] | Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | BIPOLAR PLATE MATERIAL ; DUPLEX STAINLESS-STEEL ; THIN-FILMS ; ELECTROCHEMICAL-BEHAVIOR ; PREFERRED ORIENTATION ; CHLORIDE SOLUTION ; PITTING BEHAVIOR ; TEMPERATURE ; PEMFC ; ALLOY |
| 收录类别 | SCI ; EI |
| 原文出处 | http://dx.doi.org/10.1016/j.jpowsour.2015.08.024 |
| 语种 | 英语 |
| WOS记录号 | WOS:000361772600044 |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/58414]  |
| 专题 | 力学研究所_先进制造工艺力学重点实验室 |
| 推荐引用方式 GB/T 7714 | Xu J,Li ZY,Xu S,et al. A nanocrystalline zirconium carbide coating as a functional corrosion-resistant barrier for polymer electrolyte membrane fuel cell application[J]. JOURNAL OF POWER SOURCES,2015,297:359-369. |
| APA | Xu J,李正阳,Xu S,Munroe P,&Xie ZH.(2015).A nanocrystalline zirconium carbide coating as a functional corrosion-resistant barrier for polymer electrolyte membrane fuel cell application.JOURNAL OF POWER SOURCES,297,359-369. |
| MLA | Xu J,et al."A nanocrystalline zirconium carbide coating as a functional corrosion-resistant barrier for polymer electrolyte membrane fuel cell application".JOURNAL OF POWER SOURCES 297(2015):359-369. |
入库方式： OAI收割
来源：力学研究所
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