Photoelectron Imaging Spectroscopy of AuC3H- Anions: Four Isomers
文献类型:期刊论文
作者 | Meng, Jing-Heng1,2; Liu, Qing-Yu1,2; He, Sheng-Gui1 |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY A |
出版日期 | 2015-11-19 |
卷号 | 119期号:46页码:11265-11270 |
英文摘要 | Laser ablation gnerated AuC3H- anions were skimmed into a time-offlight mass spectrometer (TOF-MS) and selected with a mass gate. Photoelectron spectra of AuC3H- were recorded using the velocity map imaging tethnique at several photon energies. The experimental spectra, quantum chemistry calculations, and Franck-Condon simulations suggest that the AuC3H- cluster has four structure isomers, including one unexpected structure of [C=C=C-Au-H](-). When AuC3H- is compared with C3H2-, introduction of gold into the hydrocarbon system results in the much lower isomerization barriers. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-01-12 |
源URL | [http://ir.iccas.ac.cn/handle/121111/29357] |
专题 | 化学研究所_分子动态与稳态结构实验室 |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Meng, Jing-Heng,Liu, Qing-Yu,He, Sheng-Gui. Photoelectron Imaging Spectroscopy of AuC3H- Anions: Four Isomers[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2015,119(46):11265-11270. |
APA | Meng, Jing-Heng,Liu, Qing-Yu,&He, Sheng-Gui.(2015).Photoelectron Imaging Spectroscopy of AuC3H- Anions: Four Isomers.JOURNAL OF PHYSICAL CHEMISTRY A,119(46),11265-11270. |
MLA | Meng, Jing-Heng,et al."Photoelectron Imaging Spectroscopy of AuC3H- Anions: Four Isomers".JOURNAL OF PHYSICAL CHEMISTRY A 119.46(2015):11265-11270. |
入库方式: OAI收割
来源:化学研究所
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