Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose
文献类型：期刊论文
| 作者 | Li, Yuping1 ; Liao, Yuhe1,2; Cao, Xiaofeng1,2,3; Wang, Tiejun1; Ma, Longlong1; Long, Jinxing1; Liu, Qiying1; Xua, Ying1
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| 刊名 | biomass & bioenergy
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 74页码:148-161 |
| 关键词 | Polyols Cellulose Hydrolytic hydrogenation/hydrogenolysis Reaction pathway Catalyst |
| 英文摘要 | in this review, recent advances in the one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose to value-added polyols, including hexitols (sorbitol, mannitol, and isosorbide) and 1,2-alkanediols (ethylene glycol and 1,2-propylene glycol), are summarized. methods for the generation of h+ in the first step of cellulose hydrolysis to form intermediate sugars, such as the use of soluble acids (mineral acids and heteropoly acids) and h+ produced in situ from functional supports and h-2 dissociation, are classified and analyzed, considering its combination with active metals for the subsequent hydrogenation or hydrogenolysis of sugars to polyols. the interaction of non-noble metals such as nickel, bimetals, and tungsten with support materials in the catalytic conversion of intermediate sugars to hexitols and ethylene glycol is reviewed. the corresponding reaction pathways and mechanisms are discussed, including the conversion process using basic supports and solution conditions. major challenges and promising routes are also suggested for the future development of the chemocatalytic conversion of cellulose. (c) 2015 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
| 类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
| 研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
| 关键词[WOS] | supported carbide catalysts ; sugar alcohols ; selective conversion ; microcrystalline cellulose ; platform chemicals ; tungsten carbide ; heterogeneous catalysts ; 1,2-propylene glycol ; bimetallic catalysts ; phosphide catalysts |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351789500016 |
| 公开日期 | 2016-01-12 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/9103]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Coal Chem, Taiyuan 030001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yuping,Liao, Yuhe,Cao, Xiaofeng,et al. Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose[J]. biomass & bioenergy,2015,74:148-161. |
| APA | Li, Yuping.,Liao, Yuhe.,Cao, Xiaofeng.,Wang, Tiejun.,Ma, Longlong.,...&Xua, Ying.(2015).Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose.biomass & bioenergy,74,148-161. |
| MLA | Li, Yuping,et al."Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose".biomass & bioenergy 74(2015):148-161. |
入库方式： OAI收割
来源：广州能源研究所
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