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Effect of torrefaction on structure and fast pyrolysis behavior of corncobs

文献类型:期刊论文

作者Zheng, Anqing; Zhao, Zengli; Chang, Sheng; Huang, Zhen; Wang, Xiaobo; He, Fang; Li, Haibin
刊名bioresource technology
出版日期2013
卷号128页码:370-377
关键词Torrefaction Fast pyrolysis Bio-oil C-13 NMR Pyrolysis mechanism
英文摘要pretreatment of corncobs using torrefaction was conducted in an auger reactor at 250-300 degrees c and residence times of 10-60 min. the torrefied corncobs were fast pyrolyzed in a bubbling fluidized bed reactor at 470 degrees c to obtain high-quality bio-oil. the heating value and ph of the bio-oil improved when the torrefaction as pretreatment was applied; however, increasing bio-oil yield penalties were observed with increasing torrefaction severity. fourier transform infrared spectroscopy (ftir) and quantitative solid c-13 nuclear magnetic resonance spectrometry (nmr) analysis of torrefied corncobs showed that the devolatilization, crosslinking and charring of corncobs during torrefaction could be responsible for the bio-oil yield penalties. gas chromatography-mass spectrometry (gc-ms) analysis showed that the acetic acid and furfural contents of the bio-oil decreased with torrefaction temperature or residence time. the results showed that torrefaction is an effective method of pretreatment for improving bio-oil quality if the crosslinking and charring of biomass can be restricted. (c) 2012 elsevier ltd. all rights reserved.
WOS标题词science & technology ; life sciences & biomedicine ; technology
类目[WOS]agricultural engineering ; biotechnology & applied microbiology ; energy & fuels
研究领域[WOS]agriculture ; biotechnology & applied microbiology ; energy & fuels
关键词[WOS]mallee woody biomass ; bio-oil ; cellulose ; pretreatment ; temperature ; products ; kinetics ; gasoline ; water ; acid
收录类别SCI
语种英语
WOS记录号WOS:000315545800053
源URL[http://ir.giec.ac.cn/handle/344007/9120]  
专题中国科学院广州能源研究所
作者单位Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714
Zheng, Anqing,Zhao, Zengli,Chang, Sheng,et al. Effect of torrefaction on structure and fast pyrolysis behavior of corncobs[J]. bioresource technology,2013,128:370-377.
APA Zheng, Anqing.,Zhao, Zengli.,Chang, Sheng.,Huang, Zhen.,Wang, Xiaobo.,...&Li, Haibin.(2013).Effect of torrefaction on structure and fast pyrolysis behavior of corncobs.bioresource technology,128,370-377.
MLA Zheng, Anqing,et al."Effect of torrefaction on structure and fast pyrolysis behavior of corncobs".bioresource technology 128(2013):370-377.

入库方式: OAI收割

来源:广州能源研究所

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