Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells
文献类型：期刊论文
| 作者 | Wang Hai1,2; Xu Xue-Qing1 ; Shi Ji-Fu1; Xu Gang1
|
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 2013-03-01 |
| 卷号 | 29期号:3页码:525-532 |
| 关键词 | Ionic liquid Viscosity Electrolyte Conductivity Dye-sensitized solar cell |
| 英文摘要 | a method of utilizing p-pi conjugation effects for obtaining low-viscosity ionic liquids is presented. p-pi conjugation effectively disperses anionic charge and reduces coulombic interactions. ionic liquids prepared in this study were 1-ethyl-3-methylimidazolium benzoate (emib) and 1-ethyl-3-methylimidazolium isonicotinate (emiin). they have carboxyl and aromatic ring p-pi conjugated anions, and achieve low viscosities of 42 and 27 mpa . s, respectively. emib and emiin were employed as electrolytes, which were used to construct dye-sensitized solar cells (dscs). after optimizing the composition, the ionic conductivity and triiodide ionic diffusion constant for the emib-based electrolyte were 1.43 ms . cm(-1) and 1.45 x 10(-7) cm(2) . s(-1), respectively. for the emiin-based electrolyte, the ionic conductivity and triiodide ionic diffusion constant were 1.63 ms . cm(-1) and 2.01x10(-7) cm(2) . s(-1), respectively. these were higher than the corresponding values for the emib-based electrolyte because of emiin's lower viscosity. dscs based on these two electrolytes attained satisfactory energy conversion efficiencies of 2.85% and 4.30% for emib and emiin, respectively, under an illumination intensity of 300 w . m(-2). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | temperature molten-salts ; photovoltaic performance ; organic-dyes ; electrolyte ; efficiency ; conversion ; iodide ; power |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000315584400011 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/9141]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Hai,Xu Xue-Qing,Shi Ji-Fu,et al. Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells[J]. acta physico-chimica sinica,2013,29(3):525-532. |
| APA | Wang Hai,Xu Xue-Qing,Shi Ji-Fu,&Xu Gang.(2013).Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells.acta physico-chimica sinica,29(3),525-532. |
| MLA | Wang Hai,et al."Application of Ionic Liquids with Carboxyl and Aromatic Ring Conjugated Anions in Dye-Sensitized Solar Cells".acta physico-chimica sinica 29.3(2013):525-532. |
入库方式： OAI收割
来源：广州能源研究所
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