Nitrate Combustion Methods to Prepare Highly Active Cu/ZnO Catalysts for Low-Temperature Methanol Synthesis: Comparative Behaviors of Citric Acid in Air or Argon Atmosphere
文献类型：期刊论文
| 作者 | Zeng, Chunyang2; Shi, Lei1,2; Sun, Jian2; Yoneyama, Yoshiharu2; Wang, Tiejun3 ; Tsubaki, Noritatsu2,4
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| 刊名 | bulletin of the chemical society of japan
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| 出版日期 | 2013-10-15 |
| 卷号 | 86期号:10页码:1202-1209 |
| 英文摘要 | a citric acid-assisted solid-state method is developed to prepare highly active cu/zno catalysts in different atmospheres (air and argon). the entire catalyst preparation process is accomplished with inexpensive raw materials. it is environmentally friendly in that no water is used and no waste water is produced during the entire process. these as-prepared catalysts are investigated in low-temperature methanol synthesis with co2-containing syngas. the properties of these catalysts are systematically studied by thermogravimetry differential thermal analysis, x-ray diffraction, fourier transform-infrared spectroscopy, raman spectroscopy, temperature-programmed reduction, brunauer-emmett-teller, and n2o chemisorption techniques. the activity and methanol selectivity of cu/zno catalysts are closely related to the metallic cu-0 surface areas and cu crystalline sizes. compared with traditional solid-state or sol-gel autocombustion methods, the catalysts prepared by this citric acid-assisted solid-state method exhibit much higher activity and methanol selectivity. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | auto-combustion ; fuel-cell ; raman ; powders ; carbon ; precursor ; hydrogen |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000326481100012 |
| 公开日期 | 2016-01-12 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/9165]  |
| 专题 | 中国科学院广州能源研究所 生物质化工品制备实验室 |
| 作者单位 | 1.Shenyang Univ Chem Technol, Dept Appl Chem, Shenyang 110142, Peoples R China 2.Toyama Univ, Sch Engn, Dept Appl Chem, Toyama 9308555, Japan 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 4.JST, ACT C, Kawaguchi, Saitama 3320012, Japan |
| 推荐引用方式 GB/T 7714 | Zeng, Chunyang,Shi, Lei,Sun, Jian,et al. Nitrate Combustion Methods to Prepare Highly Active Cu/ZnO Catalysts for Low-Temperature Methanol Synthesis: Comparative Behaviors of Citric Acid in Air or Argon Atmosphere[J]. bulletin of the chemical society of japan,2013,86(10):1202-1209. |
| APA | Zeng, Chunyang,Shi, Lei,Sun, Jian,Yoneyama, Yoshiharu,Wang, Tiejun,&Tsubaki, Noritatsu.(2013).Nitrate Combustion Methods to Prepare Highly Active Cu/ZnO Catalysts for Low-Temperature Methanol Synthesis: Comparative Behaviors of Citric Acid in Air or Argon Atmosphere.bulletin of the chemical society of japan,86(10),1202-1209. |
| MLA | Zeng, Chunyang,et al."Nitrate Combustion Methods to Prepare Highly Active Cu/ZnO Catalysts for Low-Temperature Methanol Synthesis: Comparative Behaviors of Citric Acid in Air or Argon Atmosphere".bulletin of the chemical society of japan 86.10(2013):1202-1209. |
入库方式： OAI收割
来源：广州能源研究所
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