Metal-Organic Frameworks Hkust-1 for Liquid-Phase Adsorption of Uranium
文献类型：期刊论文
| 作者 | Feng YF(冯亚菲) ; Jiang H(姜恒); Li SN; Wang J; Jing XY; Wang YR(王育人); Chen M(陈猛)
|
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2013 |
| 卷号 | 431页码:87-92 |
| 通讯作者邮箱 | yurenwang@imech.ac.cn |
| 关键词 | Metal-organic frameworks HKUST-1 Liquid-phase adsorption Uranium |
| ISSN号 | 0927-7757 |
| 产权排序 | [Feng, Yafei; Li, Songnan; Wang, Jun; Jing, Xiaoyan] Harbin Engn Univ, Minist Educ, Key Lab Super Light Mat & Surface Technol, Harbin 150001, Peoples R China; [Jiang, Heng; Wang, Yuren; Chen, Meng] Chinese Acad Sci, Inst Mech, Key Lab Micrograv Sci, Beijing 100190, Peoples R China |
| 通讯作者 | Wang, YR (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv Sci, Beijing 100190, Peoples R China. |
| 中文摘要 | This paper reports on the efficient adsorption for uranium by metal-organic frameworks (MOFs) HKUST-1 from aqueous solution. The structure of the prepared HKUST-1 was characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption/desorption analysis. The influences of different experimental parameters were studied, such as initial solution pH, adsorbent dosage, adsorption time, temperature and various concentrations of uranium uptake. The thermodynamic parameters including Gibbs free energy (Delta G(0)), standard enthalpy change (Delta H-0) and standard entropy change (Delta S-0) for the process were calculated using the Langmuir constants. The results showed that the equilibrium data fitted well to Langmuir model in the studied range of uranium concentration (10 mg/L-800 mg/L) and temperature (298 K-318 K), and the HKUST-1 exhibited the highest uptake for uranium at 318 K, at the initial solution pH value of 6 and at the initial uranium concentration of 800 mg/L. The thermodynamics of uranium/HKUST-1 system indicated the spontaneous and endothermic nature of the process. And the kinetics of the adsorption process followed the pseudo-second-order kinetics model. (C) 2013 Elsevier B.V. All rights reserved. |
| 分类号 | Q3 |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | MICROPOROUS COORDINATION POLYMERS ; AQUEOUS-SOLUTIONS ; REMOVAL ; SORPTION ; CU-3(BTC)(2) ; ACTIVATION ; STABILITY ; WATER ; ADSORBENTS ; EFFICIENT |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000321417900012 |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/58577]  |
| 专题 | 力学研究所_国家微重力实验室 |
| 推荐引用方式 GB/T 7714 | Feng YF,Jiang H,Li SN,et al. Metal-Organic Frameworks Hkust-1 for Liquid-Phase Adsorption of Uranium[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2013,431:87-92. |
| APA | 冯亚菲.,姜恒.,Li SN.,Wang J.,Jing XY.,...&陈猛.(2013).Metal-Organic Frameworks Hkust-1 for Liquid-Phase Adsorption of Uranium.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,431,87-92. |
| MLA | 冯亚菲,et al."Metal-Organic Frameworks Hkust-1 for Liquid-Phase Adsorption of Uranium".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 431(2013):87-92. |
入库方式： OAI收割
来源：力学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。