Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine
文献类型：期刊论文
| 作者 | Lei,Ting; Zhang,Hongbin; Yang,Yu-Rong |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2015-10-21 |
| 卷号 | 56期号:43页码:5933-5936 |
| 关键词 | Iridium-catalyzed Asymmetric amination Aurantioclavine |
| 英文摘要 | A new protocol for generating indoleazepine 9 via an Ir-catalyzed intramolecularly asymmetric amination of secondary allylic alcohol 5 in the presence of Carreira ligand (10) and Sc(OTf)(3) is described. This methodology has been exploited in the facile synthesis of natural (-)-aurantioclavine (1), a biosynthetical precursor of communesins, and its unnatural enantiomer (+)-aurantioclavine (ent-1). (C) 2015 Elsevier Ltd. All rights reserved. |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | DIELS-ALDER APPROACH ; ALLYLIC AMINATION ; COMMUNESIN F ; ASYMMETRIC-SYNTHESIS ; BIOMIMETIC APPROACH ; (+/-)-COMMUNESIN F ; INDOLINE ALKALOIDS ; ALPHA-ALLYLATION ; PEROPHORAMIDINE ; STRATEGY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000362919100025 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/25205]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lei,Ting,Zhang,Hongbin,Yang,Yu-Rong. Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine[J]. TETRAHEDRON LETTERS,2015,56(43):5933-5936. |
| APA | Lei,Ting,Zhang,Hongbin,&Yang,Yu-Rong.(2015).Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine.TETRAHEDRON LETTERS,56(43),5933-5936. |
| MLA | Lei,Ting,et al."Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine".TETRAHEDRON LETTERS 56.43(2015):5933-5936. |
入库方式： OAI收割
来源：昆明植物研究所
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