Selenium speciation by high-performance anion-exchange chromatography-post-column UV irradiation coupled with atomic fluorescence spectrometry
文献类型：会议论文
| 作者 | Liang, Lina; Mo, Shumin; Zhang, Ping; Cai, Yaqi; Mou, Shifen; Jiang, Guibin; Wen, Meijuan |
| 出版日期 | 2006 |
| 会议名称 | 18th International Ion Chromatography Symposium |
| 会议日期 | SEP 18-21, 2005 |
| 会议地点 | Montreal, CANADA |
| 关键词 | speciation anon-exchange chromatography atomic fluorescence spectrometry ultraviolet irradiation selenium |
| 英文摘要 | A technique for the speciation of selenomethylcysteine (SeMeCys), selenocystine (SeCys), selenite [Se(IV)] and selenomethionine (SeMet) was established in this paper using high-performance anion-exchange chromatography coupled with atomic fluorescence spectrometry (HPAEC-AFS). Analytes were separated on an AminoPac PA10 column and then digested by on-line ultraviolet (UV) irradiation, which destroyed organic compound structure. Hydride generation was used as an available sample introduction technique for atomic fluorescence detection. The detection limits of four compounds were 1-5 mu g/L (250 mu L injection, 10 times of the baseline noise). The relative standard deviations (RSDs), calculated from seven consecutive injections of 100 mu g/L standard mixtures, were from 2 to 4%. Selenious yeast tablet, which had been proposed as selenium supplement, and human urine collected from a volunteer were analyzed. Good spiked recoveries from 86 to 103% were obtained. (c) 2006 Elsevier B.V. All rights reserved. |
| ISSN号 | 0021-9673 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/24745]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Liang, Lina,Mo, Shumin,Zhang, Ping,et al. Selenium speciation by high-performance anion-exchange chromatography-post-column UV irradiation coupled with atomic fluorescence spectrometry[C]. 见:18th International Ion Chromatography Symposium. Montreal, CANADA. SEP 18-21, 2005. |
入库方式： OAI收割
来源：生态环境研究中心
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