Dye-Sensitized NiSx Catalyst Decorated on Graphene for Highly Efficient Reduction of Water to Hydrogen under Visible Light Irradiation
文献类型：期刊论文
| 作者 | Kong C(孔超)1,2 ; Min SX(敏世雄)1,2; Lv GX(吕功煊)1
|
| 刊名 | ACS Catalysis
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:8页码:2763-2769 |
| 关键词 | NiSx graphene dye photocatalyst visible light hydrogen generation sensitized |
| ISSN号 | 2155-5435 |
| 通讯作者 | 吕功煊 |
| 英文摘要 | In this work, a highly active H2 evolution NiSx catalyst decorated on graphene (NiSx/G) nanohybrid was prepared by an in situ chemical deposition method, in which nickel ion was first adsorbed onto graphene and subsequently reacted with sulfide ion to yield the NiSx/G nanohybrid. The NiSx/G catalyst exhibited activity for hydrogen generation 2-fold higher than that of pristine NiSx under visible light irradiation. The highest quantum efficiency of 32.5% was reached at 430 nm when Eosin Y was used as a photosensitizer. In this system, graphene not only provided a large area and two-dimensional substrate for the confined growth of NiSx but also greatly enhanced the transfer of photoelectrons from excited Eosin Y to the NiSx cocatalyst because of its promotion of charge separation, leading to the great enhancement of photocatalytic hydrogen evolution. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the 973 and 863 Programof Depantment of sciences and technology of China (2013CB632404;2012AA051501;2009CB220003);the NSF of China (grant no. 21173242) |
| 语种 | 英语 |
| WOS记录号 | WOS:000339983800046 |
| 源URL | [http://210.77.64.217/handle/362003/19249]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong C,Min SX,Lv GX. Dye-Sensitized NiSx Catalyst Decorated on Graphene for Highly Efficient Reduction of Water to Hydrogen under Visible Light Irradiation[J]. ACS Catalysis,2014,4(8):2763-2769. |
| APA | Kong C,Min SX,&Lv GX.(2014).Dye-Sensitized NiSx Catalyst Decorated on Graphene for Highly Efficient Reduction of Water to Hydrogen under Visible Light Irradiation.ACS Catalysis,4(8),2763-2769. |
| MLA | Kong C,et al."Dye-Sensitized NiSx Catalyst Decorated on Graphene for Highly Efficient Reduction of Water to Hydrogen under Visible Light Irradiation".ACS Catalysis 4.8(2014):2763-2769. |
入库方式： OAI收割
来源：兰州化学物理研究所
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