Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions
文献类型：期刊论文
| 作者 | Ke ZG(柯振刚)1,2 ; Zhang Y(张妍)1; Cui XJ(崔新江)1; Shi F(石峰)1
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| 刊名 | Green Chemistry
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| 出版日期 | 2016 |
| 卷号 | 18期号:3页码:808-816 |
| 关键词 | N-formylation Paraformaldehyde Au/Al2O3 catalyst |
| ISSN号 | 1463-9262 |
| 通讯作者 | 石峰 |
| 英文摘要 | A simple and efficient Au/Al2O3 catalyst was prepared by the co-precipitation method for the oxidative N-formylation of amines with paraformaldehyde. Under the optimized reaction conditions, excellent amine conversion and N-formamide selectivity can be obtained with up to 97% yield with water as the solvent under ambient conditions. This catalyst tolerated a wide range of primary amines and second amines, and it can be reused for at least five runs without obvious deactivation. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21203219);Youth Innovation Promotion Association CAS |
| 语种 | 英语 |
| WOS记录号 | WOS:000369535100029 |
| 源URL | [http://210.77.64.217/handle/362003/19042]  |
| 专题 | 兰州化学物理研究所_绿色化学研究发展中心 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ke ZG,Zhang Y,Cui XJ,et al. Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions[J]. Green Chemistry,2016,18(3):808-816. |
| APA | Ke ZG,Zhang Y,Cui XJ,&Shi F.(2016).Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions.Green Chemistry,18(3),808-816. |
| MLA | Ke ZG,et al."Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions".Green Chemistry 18.3(2016):808-816. |
入库方式： OAI收割
来源：兰州化学物理研究所
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