INVESTIGATION OF THE MITSUNOBU REACTION OF BINOL AND CINCHONA ALKALOIDS: INVERSION OR RETENTION OF CONFIGURATION?
文献类型：期刊论文
| 作者 | Yang, Wei1; Cui, Yu-Ming1; Zou, Jing-Feng1; Wang, Cai-Yun1; Huang, Wei-Sheng1; Zhang, Jin1; Xu LW(徐利文)1,2 |
| 刊名 | Synthetic Communications
 |
| 出版日期 | 2014 |
| 卷号 | 44期号:21页码:3173-3182 |
| 关键词 | BINOL cinchona alkaloids inversion Mitsunobu reaction multistereogenic chirality retention |
| ISSN号 | 0039-7911 |
| 通讯作者 | Cui, Yu-Ming ; 徐利文 |
| 英文摘要 | An efficient approach toward the construction of multistereogenic binaphthol (BINOL)–derived alkaloids with C2-axial and sp3 central chirality has been accomplished. The reaction of BINOL and cinchona alkaloids was occurred smoothly under the Mitsunobu conditions, which led to the synthesis of a new family of complicated functional molecules based on chiral BINOL and cinchona alkaloids. In addition, on the basis of the experimental results, we provided a possible explanation for the intramolecular tertiary amine-induced retention of configuration at C9 of cinchona alkaloids while the inversion of configuration was observed with general alcohols under classic Mitsunobu conditions. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 21173064;51303043);Zhejiang Provincial Natural Science Foundation of China (LR14B030001);Hangzhou Science and Technology Program (20130432B06;20130533B15) |
| 语种 | 英语 |
| WOS记录号 | WOS:000341515200010 |
| 源URL | [http://210.77.64.217/handle/362003/19233]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Wei,Cui, Yu-Ming,Zou, Jing-Feng,et al. INVESTIGATION OF THE MITSUNOBU REACTION OF BINOL AND CINCHONA ALKALOIDS: INVERSION OR RETENTION OF CONFIGURATION?[J]. Synthetic Communications,2014,44(21):3173-3182. |
| APA | Yang, Wei.,Cui, Yu-Ming.,Zou, Jing-Feng.,Wang, Cai-Yun.,Huang, Wei-Sheng.,...&Xu LW.(2014).INVESTIGATION OF THE MITSUNOBU REACTION OF BINOL AND CINCHONA ALKALOIDS: INVERSION OR RETENTION OF CONFIGURATION?.Synthetic Communications,44(21),3173-3182. |
| MLA | Yang, Wei,et al."INVESTIGATION OF THE MITSUNOBU REACTION OF BINOL AND CINCHONA ALKALOIDS: INVERSION OR RETENTION OF CONFIGURATION?".Synthetic Communications 44.21(2014):3173-3182. |
入库方式： OAI收割
来源：兰州化学物理研究所
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