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Nickel-catalyzed oxidative cross-coupling of arylboronic acids with olefins

文献类型：期刊论文

作者Liu, Dong1; Liu C(刘超)1; Lei AW(雷爱文)1,2
刊名Pure and Applied Chemistry
出版日期2014
卷号86期号:3页码:321-328
关键词arylboronic acids 1 nickel OMCOS-17 oxidative cross-coupling radical pathway 2-diarylalkenes
ISSN号0033-4545
通讯作者雷爱文
英文摘要A novel and efficient nickel-catalyzed oxidative cross-coupling of arylboronic acids with olefins to synthesize 1,2-diarylalkenes has been developed. By employing Ni(acac)2 as the catalyst, TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl) as the oxidant, a variety of arylboronic acids and styrene derivatives could be cross-coupled efficiently to afford the corresponding 1,2-diarylalkenes in moderate-to-good yields. Notably, high E-selectivity of 1,2-diarylalkenes was obtained with the aid of a high temperature of 120°C. Moreover, boric acid esters also proved to be efficient coupling partners. Initial mechanistic studies suggest that this reaction proceeds through a radical pathway.
学科主题物理化学与绿色催化
收录类别SCI
资助信息the 973 Program (2012CB725302);the National Natural Science Foundation of China (21025206;21272180);the China Postdoctoral Science Foundation funded project (2012M521458);the Program for Changjiang Scholars and Innovative Research Team in University (IRT1030)
语种英语
WOS记录号WOS:000339871300009
源URL[http://210.77.64.217/handle/362003/19288]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Dong,Liu C,Lei AW. Nickel-catalyzed oxidative cross-coupling of arylboronic acids with olefins[J]. Pure and Applied Chemistry,2014,86(3):321-328.
APA Liu, Dong,Liu C,&Lei AW.(2014).Nickel-catalyzed oxidative cross-coupling of arylboronic acids with olefins.Pure and Applied Chemistry,86(3),321-328.
MLA Liu, Dong,et al."Nickel-catalyzed oxidative cross-coupling of arylboronic acids with olefins".Pure and Applied Chemistry 86.3(2014):321-328.

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来源：兰州化学物理研究所

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