Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes
文献类型：期刊论文
| 作者 | He, Yu-Tao1; Wang, Qiang1; Li, Lian-Hua1; Liu XY(刘雪原)1; Xu PF(许鹏飞)1; Liang YM(梁永民)1,2 |
| 刊名 | Organic Letters
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:21页码:5188-5191 |
| ISSN号 | 1523-7060 |
| 通讯作者 | 梁永民 |
| 英文摘要 | A palladium-catalyzed aryldifluoroalkylation of alkynes with ethyl difluoroiodoacetate and arylboronic acids as reaction partners is described. The alkyne difunctionalization process provides various aryldifluoroalkylated products in one pot under mild reaction conditions. A wide range of alkynes and diverse arylboronic acids are compatible with these reaction conditions. High reaction efficiency and broad substrate scope are the notable features of this transformation. Preliminary mechanistic investigations indicate that a difluoroalkyl radical addition pathway is involved in this transformation. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation (NSF 21272101;21472074;21472073);the Fundamental Research Funds for Central Universities (lzujbky-2014-243);the "111" Project (J1103307);Program for Changjiang Scholars and Innovative Research Team in University (IRT1138) |
| 语种 | 英语 |
| WOS记录号 | WOS:000364434900011 |
| 源URL | [http://210.77.64.217/handle/362003/19079]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Yu-Tao,Wang, Qiang,Li, Lian-Hua,et al. Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes[J]. Organic Letters,2015,17(21):5188-5191. |
| APA | He, Yu-Tao,Wang, Qiang,Li, Lian-Hua,Liu XY,Xu PF,&Liang YM.(2015).Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes.Organic Letters,17(21),5188-5191. |
| MLA | He, Yu-Tao,et al."Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes".Organic Letters 17.21(2015):5188-5191. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。