Two Metal-organic Frameworks (MOFs) Assembled from One Asymmetric Semirigid Multicarboxylate Ligand: Syntheses and Crystal Structural Characterizations
文献类型：期刊论文
| 作者 | Zhao HW(赵恒武)2; Li B(李斌)1,3
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| 刊名 | 结构化学
 |
| 出版日期 | 2012 |
| 卷号 | 31期号:1页码:61-66 |
| 关键词 | copper nickel lead 3-(2-carboxy-phenoxy)-benzoic acid 4 2 1 4 '-bipyridine 2 '-bipyridine 10-phenanthroline |
| ISSN号 | 0254-5861 |
| 通讯作者 | 李斌 |
| 英文摘要 | Hydrothermal reactions between a new flexible multicarboxylate ligand of 3-(2-carboxy-phenoxy)-benzoic acid(H2L) and transitional metal cations of M2+ (M = Cu2+, Ni2+) in the presence of the secondary ligands of 1,10-phenanthroline(phen),2,2’-bipyridine(2,2’-bpy),and 4,4’-bipyridine(4,4’-bpy) afford two novel coordination polymers Ni2(H2O)2L2(phen)(μ-4,4’-bpy)(1) and CuIIL(2,2’-bpy)(2).Both compounds were characterized by X-ray crystallography.Crystal data of 1:C31H24N3NiO7, Mr = 609.24, monoclinic, space group P21/c,a = 17.560(8), b = 10.528(5), c = 30.613(15)Å,V = 5659(5) Å3,Z = 4, Dc = 1.430 g/cm3, F(000) = 502, μ = 0.739 mm-1, R = 0.0902, wR = 0.1346(I > 2σ(I)),S = 1.002. Crystal data of 2: C24H16CuN2O5, Mr = 475.93, monoclinic, space group P21/n, a = 9.8904(13), b = 11.0782(16), c = 18.321(3)Å, β = 11.0782(16)°, V = 1993.8(5) Å3, Z = 4, Dc = 1.585 g/cm3, F(000) = 972, μ = 1.137 mm-1, R = 0.0433, wR = 0.0723 (I > 2σ(I)) and S = 1.004.Compound 1 displays a one-dimensional(1D) zigzag chain structure constructed from phen ligands and the deprotonated ligands of L2-, which further forms a ladder-shaped supramolecular architecture via the bridge of 4,4’-bpy ligand.Complex 2 also possesses a ladder-shaped architecture based on the dinuclear CuII units. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the State Key Laboratory of Solid Lubrication (No. 0701);Shandong Provincial Department of Finance (No. 63[2008]) |
| 语种 | 英语 |
| WOS记录号 | WOS:000299802300010 |
| 源URL | [http://210.77.64.217/handle/362003/19325]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.Qilu Normal Univ, Dept Chem, Adv Mat Inst Res, Jinan 250013, Peoples R China 2.Zaozhuang Vocat Coll Sci & Technol, Dept Med Technol, Tengzhou 277500, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao HW,Li B. Two Metal-organic Frameworks (MOFs) Assembled from One Asymmetric Semirigid Multicarboxylate Ligand: Syntheses and Crystal Structural Characterizations[J]. 结构化学,2012,31(1):61-66. |
| APA | Zhao HW,&Li B.(2012).Two Metal-organic Frameworks (MOFs) Assembled from One Asymmetric Semirigid Multicarboxylate Ligand: Syntheses and Crystal Structural Characterizations.结构化学,31(1),61-66. |
| MLA | Zhao HW,et al."Two Metal-organic Frameworks (MOFs) Assembled from One Asymmetric Semirigid Multicarboxylate Ligand: Syntheses and Crystal Structural Characterizations".结构化学 31.1(2012):61-66. |
入库方式： OAI收割
来源：兰州化学物理研究所
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