Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids
文献类型：期刊论文
| 作者 | Zhou F(周锋)1,2 ; Liu SM(刘士民)1; Yang BQ(杨本群)1; Wang PX(王培学)1; Alshammari, Ahmad S.3; Deng YQ(邓友全)1
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| 刊名 | Electrochemistry Communications
 |
| 出版日期 | 2014 |
| 卷号 | 46页码:103-106 |
| 关键词 | Carbon dioxide Ionic liquids Silver Electrocatalysis Reduction |
| ISSN号 | 1388-2481 |
| 通讯作者 | 邓友全 |
| 英文摘要 | In this study, the electrochemical reduction of carbon dioxide (CO2) was examined in a series of aqueous solutions of ionic liquids on metal (silver (Ag), copper, platinum and gold) catalyst cathode. The results indicated that Ag metal cathode in 1-butyl-3-methylimidazolium chloride (BMImCl) with 20 wt.% water showed excellent synergy in electrochemical reduction of CO2 to carbon monoxide (CO) with extremely high selectivity (> 99%) and efficiency, and with stable area specific activity (ca. 2.4 mA·cm− 2). The behavior of electrocatalytic reduction of CO2 to CO on Ag electrode in ionic liquids (ILs) was examined by cyclic voltammogram. The study revealed that the chloride containing IL could be the most effective candidate for reduction of CO2 to CO and for inhibiting the hydrogen evolution reaction probably due to the dominated water–anion and water–cation interactions in aqueous BMImCl. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (no. 21173240) |
| 语种 | 英语 |
| WOS记录号 | WOS:000341348700027 |
| 源URL | [http://210.77.64.217/handle/362003/19274]  |
| 专题 | 兰州化学物理研究所_绿色化学研究发展中心 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.King Abdulaziz City Sci & Technol, Natl Nanotechnol Res Ctr, Riyadh 11442, Saudi Arabia |
| 推荐引用方式 GB/T 7714 | Zhou F,Liu SM,Yang BQ,et al. Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids[J]. Electrochemistry Communications,2014,46:103-106. |
| APA | Zhou F,Liu SM,Yang BQ,Wang PX,Alshammari, Ahmad S.,&Deng YQ.(2014).Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids.Electrochemistry Communications,46,103-106. |
| MLA | Zhou F,et al."Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids".Electrochemistry Communications 46(2014):103-106. |
入库方式： OAI收割
来源：兰州化学物理研究所
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