Cycloartane-type triterpenoids and sesquiterpenoids from the resinous exudates of Commiphora opobalsamum
文献类型:期刊论文
作者 | Yang JL(杨军丽)1![]() ![]() ![]() |
刊名 | Phytochemistry
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出版日期 | 2012 |
卷号 | 76页码:124-132 |
关键词 | Commiphora opobalsamum Burseraceae Cycloartane-type triterpenoids Sesquiterpenoids Cytotoxicity Single-crystal X-ray diffraction CD exciton chirality |
ISSN号 | 0031-9422 |
通讯作者 | 师彦平 |
英文摘要 | Cycloartane-type triterpenoids (1-3), seven sesquiterpenoids (7-13), and five previously reported secondary metabolites, including three cycloartane-type triterpenoids (4-6) and two sesquiterpenoids (14 and 15), were isolated from the resinous exudates of Commiphora opobalsamum. Their structures were elucidated by extensive spectroscopic analysis, including UV, IR, NMR, and MS, and comparison with literature data. The structures of 1, 3, and 7 were confirmed by single-crystal X-ray diffraction analysis. The absolute configuration of 1 was interpreted by the incorporation of CHCl3 (crystallization solvent) in the crystal and that of 10 was determined by the CD exciton chirality method. Compound 12 represents the first example of a 12-norcadinane-type sesquiterpenoid. Furthermore, compounds 1,3,7, and 10-14 were evaluated for cytotoxicity against HeLa and HepG2 cell lines. |
学科主题 | 分析化学与药物化学 |
收录类别 | SCI |
资助信息 | the Foundation for the National Natural Science Foundation of China (Nos. 20621091;20875095;21075127) |
语种 | 英语 |
WOS记录号 | WOS:000302444500015 |
公开日期 | 2016-02-26 |
源URL | [http://210.77.64.217/handle/362003/19352] ![]() |
专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
通讯作者 | Shi YP(师彦平) |
作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Key Lab Chem NW Plant Resources, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Key Lab Nat Med Gansu Prov, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Yang JL,Shi YP,Shi YP. Cycloartane-type triterpenoids and sesquiterpenoids from the resinous exudates of Commiphora opobalsamum[J]. Phytochemistry,2012,76:124-132. |
APA | Yang JL,Shi YP,&师彦平.(2012).Cycloartane-type triterpenoids and sesquiterpenoids from the resinous exudates of Commiphora opobalsamum.Phytochemistry,76,124-132. |
MLA | Yang JL,et al."Cycloartane-type triterpenoids and sesquiterpenoids from the resinous exudates of Commiphora opobalsamum".Phytochemistry 76(2012):124-132. |
入库方式: OAI收割
来源:兰州化学物理研究所
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