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C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction
文献类型：期刊论文
| 作者 | Wang, ZL; Hao, XF; Jiang, Z; Sun, XP; Xu, D; Wang, J; Zhong, HX; Meng, FL; Zhang, XB |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2015 |
| 卷号 | 137期号:48页码:15070—15073 |
| 关键词 | OXYGEN REDUCTION REACTION REDUCED GRAPHENE OXIDE DOPED CARBON IN-SITU MOLYBDENUM CARBIDE TRANSITION-METAL COBALT NANOPARTICLES POROUS CARBON CATALYSTS NITROGEN |
| ISSN号 | 0002-7863 |
| 通讯作者 | Zhang, XB (reprint author), Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China. |
| 英文摘要 | Development of an efficient hydrogen evolution reaction (HER) catalyst composed of earth-abundant elements is scientifically and technologically important for the water splitting associated with the conversion and storage of renewable energy. Herein we report a new class of Co-C-N complex bonded carbon (only 0.22 at% Co) for HER with a self-supported and three-dimensional porous structure that shows an unexpected catalytic activity with low overpotential (212 mV at 100 mA cm(-2)) and long-term stability, better than that of most traditional-metal catalysts. Experimental observations in combination with density functional theory calculations reveal that C and N hybrid coordination optimizes the charge distribution and enhances the electron transfer, which synergistically promotes the proton adsorption and reduction kinetics. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000366339900003 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24878]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, ZL,Hao, XF,Jiang, Z,et al. C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(48):15070—15073. |
| APA | Wang, ZL.,Hao, XF.,Jiang, Z.,Sun, XP.,Xu, D.,...&Zhang, XB.(2015).C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(48),15070—15073. |
| MLA | Wang, ZL,et al."C and N Hybrid Coordination Derived Co-C-N Complex as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.48(2015):15070—15073. |
入库方式： OAI收割
来源：上海应用物理研究所
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