Compressibilities of MnFe2O4 polymorphs
文献类型：期刊论文
| 作者 | Ye, LJ; Zhai, SM; Wu, X; Xu, CW; Yang, K; Higo, YJ |
| 刊名 | PHYSICS AND CHEMISTRY OF MINERALS
 |
| 出版日期 | 2015 |
| 卷号 | 42期号:7页码:569—577 |
| 关键词 | HIGH-PRESSURE PHASE EQUATION-OF-STATE RAY-POWDER DIFFRACTION MAGNETITE SPINEL TRANSITION FERRITE CRYSTAL MGAL2O4 GPA |
| ISSN号 | 0342-1791 |
| 通讯作者 | Zhai, SM (reprint author), Chinese Acad Sci, Inst Geochem, Key Lab High Temperature & High Pressure Study Ea, Guiyang 550002, Guizhou, Peoples R China. |
| 英文摘要 | The high-pressure behavior and stability of synthetic jacobsite MnFe2O4 have been investigated up to 39.55 GPa at room temperature by means of in situ synchrotron X-ray diffraction using diamond anvil cell and multi-anvil high-pressure apparatus. The MnFe2O4 spinel undergoes a phase transition at about 18 GPa to form a denser antiferromagnetic CaMn2O4-type (CMafm) polymorph. The CMafm MnFe2O4 is stable up to 39.55 GPa in this study and remains after decompression. Fitting the pressure-volume data using a third-order Birch-Murnaghan equation of state, the isothermal bulk modulus values and the first pressure derivatives were obtained as K-0 = 169.7 (35) GPa, K-0' = 2.87 (40) for spinel-type MnFe2O4 and K-0 = 149.2 (24) GPa, K-0' = 3.98 (19) for CMafm MnFe2O4, respectively. If K-0' is fixed to 4, K-0 was obtained as 160.6 (11) GPa for spinel-type MnFe2O4 and 148.9 (7) GPa for CMafm MnFe2O4. The effects of cation substitution on the isothermal bulk modulus and pressure for phase transition of Fe3+-bearing spinels were discussed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000358940200004 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24886]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Ye, LJ,Zhai, SM,Wu, X,et al. Compressibilities of MnFe2O4 polymorphs[J]. PHYSICS AND CHEMISTRY OF MINERALS,2015,42(7):569—577. |
| APA | Ye, LJ,Zhai, SM,Wu, X,Xu, CW,Yang, K,&Higo, YJ.(2015).Compressibilities of MnFe2O4 polymorphs.PHYSICS AND CHEMISTRY OF MINERALS,42(7),569—577. |
| MLA | Ye, LJ,et al."Compressibilities of MnFe2O4 polymorphs".PHYSICS AND CHEMISTRY OF MINERALS 42.7(2015):569—577. |
入库方式： OAI收割
来源：上海应用物理研究所
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