Copper Phosphate as a Cathode Material for Rechargeable Li Batteries and Its Electrochemical Reaction Mechanism
文献类型：期刊论文
| 作者 | Zhong, GM; Bai, JY; Duchesne, PN; McDonald, MJ; Li, Q; Hou, X; Tang, JA; Wang, Y; Zhao, WG; Gong, ZL |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2015 |
| 卷号 | 27期号:16页码:5736—5744 |
| 关键词 | LITHIUM-ION BATTERIES SOLID-STATE NMR X-RAY-DIFFRACTION IN-SITU HIGH-CAPACITY ELECTRODE MATERIALS FLUORIDE NANOCOMPOSITES IRON FLUORIDE SPECTROSCOPY STORAGE |
| ISSN号 | 0897-4756 |
| 通讯作者 | Yang, Y (reprint author), Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China. |
| 英文摘要 | In the search for new cathode materials for rechargeable lithium batteries, conversion-type materials have great potential because of their ability to achieve high specific capacities via the full utilization of transition metal oxidation states. Here, we report for the first time that copper phosphate can be used as a novel high-capacity cathode for rechargeable Li batteries, capable of delivering a reversible capacity of 360 mAh/g with two discharge plateaus of 2.7 and 2.1 V at 400 mA/g. The underlying reaction involves the formation as well as the oxidation of metallic Cu. The solid-state NMR, in situ XAFS, HR-TEM, and XRD results clearly indicate that Cu can react with Li3PO4 to form copper phosphate and LixCuyPO4 during the charging process, largely determining the reversibility of Cu-3(PO4)(2). This new reaction scheme provides a new venue to explore polyanion-type compounds as high-capacity cathode materials with conversion reaction processes. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000360323700035 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24888]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhong, GM,Bai, JY,Duchesne, PN,et al. Copper Phosphate as a Cathode Material for Rechargeable Li Batteries and Its Electrochemical Reaction Mechanism[J]. CHEMISTRY OF MATERIALS,2015,27(16):5736—5744. |
| APA | Zhong, GM.,Bai, JY.,Duchesne, PN.,McDonald, MJ.,Li, Q.,...&Yang, Y.(2015).Copper Phosphate as a Cathode Material for Rechargeable Li Batteries and Its Electrochemical Reaction Mechanism.CHEMISTRY OF MATERIALS,27(16),5736—5744. |
| MLA | Zhong, GM,et al."Copper Phosphate as a Cathode Material for Rechargeable Li Batteries and Its Electrochemical Reaction Mechanism".CHEMISTRY OF MATERIALS 27.16(2015):5736—5744. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。