Electrochemical investigation of the stable chromium species in molten FLINAK
文献类型：期刊论文
| 作者 | Peng, H; Shen, M; Wang, CY; Su, T; Zuo, Y; Xie, LD |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:94页码:76689—76695 |
| 关键词 | SQUARE WAVE VOLTAMMETRY OXIDE IONS NUCLEAR APPLICATIONS REACTIVE ELECTRODES HYDROGEN FLUORIDE SALT CORROSION LIF-CAF2 THORIUM INERT |
| ISSN号 | 2046-2069 |
| 通讯作者 | Xie, LD (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
| 英文摘要 | The electrochemical behavior of Cr(III) in FLINAK melts at 600 degrees C was studied through cyclic voltammetry (CV) and square wave voltammetry (SWV). Cr(III) reduction proceeded in two steps: initial Cr(III) reduction to Cr(II) followed by subsequent reduction to Cr. The peak corresponding to the reduction of Cr(III) to Cr(II) was also observed in SWVs and CVs even though only CrF2 was added to the FLINAK melts. This result confirms that Cr(II) was converted to Cr(III) via disproportion: 3Cr(II) = 2Cr(III) + Cr. Such a conversion could be attributed to the formation of the stable species [CrF6](3-), as determined through Raman spectroscopy. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000361559700004 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24914]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Peng, H,Shen, M,Wang, CY,et al. Electrochemical investigation of the stable chromium species in molten FLINAK[J]. RSC ADVANCES,2015,5(94):76689—76695. |
| APA | Peng, H,Shen, M,Wang, CY,Su, T,Zuo, Y,&Xie, LD.(2015).Electrochemical investigation of the stable chromium species in molten FLINAK.RSC ADVANCES,5(94),76689—76695. |
| MLA | Peng, H,et al."Electrochemical investigation of the stable chromium species in molten FLINAK".RSC ADVANCES 5.94(2015):76689—76695. |
入库方式： OAI收割
来源：上海应用物理研究所
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