Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation
文献类型：期刊论文
| 作者 | Ao, YY; Xu, M; Peng, J; Li, JQ; Zhai, ML; Wu, GZ |
| 刊名 | NUCLEAR SCIENCE AND TECHNIQUES
 |
| 出版日期 | 2015 |
| 卷号 | 26期号:3页码:— |
| 关键词 | TEMPERATURE IONIC LIQUIDS INDUCED REDOX REACTIONS SOLVENT-EXTRACTION CONSTITUENT IONS STRONTIUM IONS RADIATION HEXAFLUOROPHOSPHATE FRAGMENTATION STABILITY ANIONS |
| ISSN号 | 1001-8042 |
| 通讯作者 | Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China. |
| 英文摘要 | The trace water-soluble radiolytic products of neat 1-butyl-3-methylimidazolium hexafluorophosphate ([C(4)mim][PF6]) were identified by analysing water-washed samples of gamma-irradiated ionic liquids. HF and difluorophosphinic acid were confirmed as the main radiolytic products of [C(4)mim][PF6], and their radiation chemical yields were quantified by F-19 NMR (G(F-) = 0.14 mu mol/J, G(HOP(O)F-2) = 0.053 mu mol/J). Compared to [C(4)mim][NTf2], [C(4)mim][PF6] shows better radiation stability. |
| 语种 | 英语 |
| WOS记录号 | WOS:000358109700009 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/24948]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Ao, YY,Xu, M,Peng, J,et al. Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation[J]. NUCLEAR SCIENCE AND TECHNIQUES,2015,26(3):—. |
| APA | Ao, YY,Xu, M,Peng, J,Li, JQ,Zhai, ML,&Wu, GZ.(2015).Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation.NUCLEAR SCIENCE AND TECHNIQUES,26(3),—. |
| MLA | Ao, YY,et al."Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation".NUCLEAR SCIENCE AND TECHNIQUES 26.3(2015):—. |
入库方式： OAI收割
来源：上海应用物理研究所
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