Non-corrosive green lubricants: strengthened lignin-[choline][amino acid] ionic liquids interaction via reciprocal hydrogen bonding
文献类型：期刊论文
| 作者 | Mu, LW; Shi, YJ; Guo, XJ; Ji, T; Chen, L; Yuan, RX; Brisbin, L; Wang, HY; Zhu, JH |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:81页码:66067—66072 |
| 关键词 | AMINO-ACIDS ANTIOXIDANT ACTIVITY LIGNIN BIOMATERIALS PRETREATMENT EXTRACTION DENSITY |
| ISSN号 | 2046-2069 |
| 通讯作者 | Zhu, JH (reprint author), Univ Akron, Dept Chem & Biomol Engn, Intelligent Composites Lab, Akron, OH 44325 USA. |
| 英文摘要 | A series of novel green lubricants with dissolved lignin in [choline][amino acid] ([CH][AA]) ionic liquids (ILs) have been synthesized in this work. The effect of lignin on the thermal and tribological properties of the lignin/[CH][AA] lubricants was systematically investigated by means of thermogravimetric analysis, differential scanning calorimetry, and a friction and wear tester. The lignin in [CH][AA] has been demonstrated to be an effective additive to improve thermal stability, reduce the wear rates and stabilize the friction coefficients of lignin/[CH][AA] lubricants. Density function theory calculations on the electronic structure of [CH][AA] ILs reveal the atomic natural charge of ILs and their hydrogen bonding capability with lignin. Moreover, these green lubricants show excellent anti-corrosive properties against commercial aluminum and iron boards. The strong physical adsorption of [CH][AA] ILs onto the steel surface and the reciprocal hydrogen bonding between [CH][AA] ILs and lignin synergistically contribute to the enhanced lubrication film strength and thus the tribological properties of these new lubricants. This work provides a new perspective on utilizing complete bio-products in advanced tribological lubrication systems. In addition, this will open a new application venue for lignin to improve product value in lignocellulosic biomass utilization. |
| 语种 | 英语 |
| WOS记录号 | WOS:000359243000052 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/25004]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Mu, LW,Shi, YJ,Guo, XJ,et al. Non-corrosive green lubricants: strengthened lignin-[choline][amino acid] ionic liquids interaction via reciprocal hydrogen bonding[J]. RSC ADVANCES,2015,5(81):66067—66072. |
| APA | Mu, LW.,Shi, YJ.,Guo, XJ.,Ji, T.,Chen, L.,...&Zhu, JH.(2015).Non-corrosive green lubricants: strengthened lignin-[choline][amino acid] ionic liquids interaction via reciprocal hydrogen bonding.RSC ADVANCES,5(81),66067—66072. |
| MLA | Mu, LW,et al."Non-corrosive green lubricants: strengthened lignin-[choline][amino acid] ionic liquids interaction via reciprocal hydrogen bonding".RSC ADVANCES 5.81(2015):66067—66072. |
入库方式： OAI收割
来源：上海应用物理研究所
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