Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system
文献类型：期刊论文
| 作者 | Wang, K; Fei, ZJ; Wang, J; Wu, Z; Li, CH; Xie, LD |
| 刊名 | MATERIALS CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2015 |
| 卷号 | 163页码:73—87 |
| 关键词 | QUASI-CHEMICAL MODEL ELECTROMOTIVE-FORCE MEASUREMENTS SILVER-CHLORIDE AGCL-KCL POTASSIUM-CHLORIDE HALIDE MIXTURES SALT SYSTEMS OPTIMIZATION TRICHLORIDE PSEUDOPOTENTIALS |
| ISSN号 | 0254-0584 |
| 通讯作者 | Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
| 英文摘要 | The present investigation is aimed at deriving a set of self-consistent thermodynamic functions for the AgCl-CoCl2-InCl3-KCl quaternary system within the framework of the CALPHAD approach. All the previous reported thermodynamic parameters for the binary subsystems were initially reviewed and adopted, and critical thermodynamic evaluations and optimizations were later performed on the unavailable AgCl-KCl and InCl3-KCl systems in terms of the required phase equilibria and thermochemical data from experimental measurements and theoretical predictions (First-principles method and empirical equation). The Modified Quasi-Chemical model were applied to describing the molten salt phase, while all the intermediate phases were treated as the stoichiometric compounds due to no observation of the homogeneity composition range. Various phase equilibria and thermodynamic properties in the ternary and quaternary systems could be facilely calculated based upon the ultimate thermodynamic database established in this case, which will support beneficial instructions in the related industrial processes. (C) 2015 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000365361500009 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/25081]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, K,Fei, ZJ,Wang, J,et al. Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system[J]. MATERIALS CHEMISTRY AND PHYSICS,2015,163:73—87. |
| APA | Wang, K,Fei, ZJ,Wang, J,Wu, Z,Li, CH,&Xie, LD.(2015).Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system.MATERIALS CHEMISTRY AND PHYSICS,163,73—87. |
| MLA | Wang, K,et al."Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system".MATERIALS CHEMISTRY AND PHYSICS 163(2015):73—87. |
入库方式： OAI收割
来源：上海应用物理研究所
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