Visible-light-driven dye degradation using a floriated ZnIn2S4/AgIn5S8 heteromicrosphere catalyst
文献类型：期刊论文
| 作者 | Song, JLQ; Jiang, TT; Ji, GW; Zhang, WT; Cheng, XY; Weng, W; Zhu, LX; Xu, XL |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:116页码:95943—95952 |
| 关键词 | SOLID-SOLUTION PHOTOCATALYSTS PARTIAL CATION-EXCHANGE AG2S QUANTUM DOTS IN-S ZNIN2S4 MICROSPHERES AQUEOUS SYNTHESIS FACILE SYNTHESIS H-2 EVOLUTION NANOCRYSTALS NANOPARTICLES |
| ISSN号 | 2046-2069 |
| 通讯作者 | Song, JLQ (reprint author), Univ Sci & Technol China, Chinese Acad Sci, Key Lab Strongly Coupled Quantum Matter Phys, Hefei 230026, Anhui, Peoples R China. |
| 英文摘要 | We report the synthesis of ZnIn2S4/AgIn5S8 (ZIS/AIS) heteromicrospheres with tailorable composition and controllable band gap via partial cation exchange for the first time. Detailed studies of the as-prepared samples were carried out using SEM, TEM, STEM-EDS, XRD and layer-by-layer depth XPS analysis. Based on these results, possible cation exchange was proposed, and a critical concentration of Ag+ in the crystals was identified, below which cation exchange cannot occur. Besides, an enhanced photodegradation mechanism was discussed by analyzing the UV-vis-NIR reflectance spectra and the band structure, illustrating that an appropriate thickness of the AIS layer is beneficial to the generation of active species thus favoring the degradation reaction. Further application of dye degradation demonstrated a remarkable photodegradation rate up to 99.2%. Our results shed light on how the cation exchange occurs between ternary and binary crystals, which may open a new avenue to the field for synthesizing materials at the micro-scale. |
| 语种 | 英语 |
| WOS记录号 | WOS:000364907300065 |
| 公开日期 | 2016-03-08 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/25095]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Song, JLQ,Jiang, TT,Ji, GW,et al. Visible-light-driven dye degradation using a floriated ZnIn2S4/AgIn5S8 heteromicrosphere catalyst[J]. RSC ADVANCES,2015,5(116):95943—95952. |
| APA | Song, JLQ.,Jiang, TT.,Ji, GW.,Zhang, WT.,Cheng, XY.,...&Xu, XL.(2015).Visible-light-driven dye degradation using a floriated ZnIn2S4/AgIn5S8 heteromicrosphere catalyst.RSC ADVANCES,5(116),95943—95952. |
| MLA | Song, JLQ,et al."Visible-light-driven dye degradation using a floriated ZnIn2S4/AgIn5S8 heteromicrosphere catalyst".RSC ADVANCES 5.116(2015):95943—95952. |
入库方式： OAI收割
来源：上海应用物理研究所
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