Trichlorozirconium eta (2)-hydrazonides: Synthesis, characterization and their catalytic behavior toward ethylene polymerization
文献类型：期刊论文
| 作者 | Duan, Xin-e1,2,3,4; Xing, Qi-feng3,4; Dong, Zhen-ming1; Chao, Jian-bin2; Bai, Sheng-di2; Liu, Dian-sheng2; Sun, Wen-hua3,4
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| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
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| 出版日期 | 2016-03-01 |
| 卷号 | 34期号:3页码:390-398 |
| 关键词 | Titanium complexes Phenylhydrazonide Ethylene polymerization Ultra-high molecular weight polyethylene |
| 英文摘要 | The trichlorozirconium eta (2)-hydrazonides (R=H, A; R=CH3, B) were synthesized through the finely controlled stoichiometrical reactions of anhydrous zirconium tetrachloride with the lithium salt of either 1-(furan-2-ylmethylene)-2-phenylhydrazonide or 1-(furan-2-ylethylidene)-2-phenyl hydrazonide in the solvent tetrahydrofuran (THF), respectively. These complexes were highly sensitive to air and moisture due to solely using less bulky ligand of hydrazonides. The molecular structures of the title complexes, determined by means of single crystal X-ray diffraction, were found to be the distorted pentagonal bipyramid geometry around zirconium atom, with three chlorides and the hydrazonato ligand acting as the eta (2)-coordination mode as well as two incorporated THF molecules. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), both complexes A and B exhibited catalytic activities toward ethylene polymerization, producing polyethylenes with ultra-high molecular weights. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-03-15 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29762]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Peoples R China 2.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China 3.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Xin-e,Xing, Qi-feng,Dong, Zhen-ming,et al. Trichlorozirconium eta (2)-hydrazonides: Synthesis, characterization and their catalytic behavior toward ethylene polymerization[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2016,34(3):390-398. |
| APA | Duan, Xin-e.,Xing, Qi-feng.,Dong, Zhen-ming.,Chao, Jian-bin.,Bai, Sheng-di.,...&Sun, Wen-hua.(2016).Trichlorozirconium eta (2)-hydrazonides: Synthesis, characterization and their catalytic behavior toward ethylene polymerization.CHINESE JOURNAL OF POLYMER SCIENCE,34(3),390-398. |
| MLA | Duan, Xin-e,et al."Trichlorozirconium eta (2)-hydrazonides: Synthesis, characterization and their catalytic behavior toward ethylene polymerization".CHINESE JOURNAL OF POLYMER SCIENCE 34.3(2016):390-398. |
入库方式： OAI收割
来源：化学研究所
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