The combined disposal of 1,2,4-trichlorobenzene and nitrogen oxides using the synthesized Ce0.2TiAl alpha Ox micro/nanomaterial
文献类型：期刊论文
| 作者 | Su, Guijin; Huang, Linyan; Liu, Sha; Lu, Huijie; Yang, Fan; Zheng, Minghui |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:2页码:1041-1051 |
| 英文摘要 | Dioxin-like chlorinated aromatics and NOx are toxic compounds that are typically co-released from thermal industrial processes. Nevertheless, there are few studies reporting their synergetic disposal technology. A designed two-step coprecipitation method was developed to synthesize a novel three-dimensional ball-like Ce-Ti-Al composite oxide (Ce0.2TiAl alpha Ox) micro/nanomaterial to simultaneously dispose 1,2,4-trichlorobenzene (1,2,4-TrCBz, as the model compound) and NO in a fixed-bed flow reactor at 300 degrees C. The prepared Ce0.2TiAl alpha Ox micro/nanomaterial exhibited superior activities to Ce0.2TiOx. This featured the relative increase of 1,2,4-TrCBz degradation and NO conversion efficiencies by 8.0-14.1% and 5.2-33.3%, respectively. NO had a positive effect on the degradation of 1,2,4-TrCBz and induced a significant increase in the activity of the Ce0.2TiAl alpha Ox catalysts. In the presence of NO, 1,2,4-TrCBz was slightly dechlorinated in a stepwise manner to monochlorobenzene and oxidized to small molecules such as formic acid. The oxidative degradation pathway of 1,2,4-TrCBz over Ce0.2TiAl alpha Ox was proposed to proceed via the Mars-van Krevelen mechanism that accounts for the high mobility of the reactive oxygen species, such as O2-, O-2(-), and O-, the unique redox properties of CeO2, the positive effect of NO, and the interactive effect among the different material components. |
| 研究领域[WOS] | Chemistry, Physical |
| WOS记录号 | WOS:000348937900046 |
| 公开日期 | 2016-03-15 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/32683]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Su, Guijin,Huang, Linyan,Liu, Sha,et al. The combined disposal of 1,2,4-trichlorobenzene and nitrogen oxides using the synthesized Ce0.2TiAl alpha Ox micro/nanomaterial[J]. CATALYSIS SCIENCE & TECHNOLOGY,2015,5(2):1041-1051. |
| APA | Su, Guijin,Huang, Linyan,Liu, Sha,Lu, Huijie,Yang, Fan,&Zheng, Minghui.(2015).The combined disposal of 1,2,4-trichlorobenzene and nitrogen oxides using the synthesized Ce0.2TiAl alpha Ox micro/nanomaterial.CATALYSIS SCIENCE & TECHNOLOGY,5(2),1041-1051. |
| MLA | Su, Guijin,et al."The combined disposal of 1,2,4-trichlorobenzene and nitrogen oxides using the synthesized Ce0.2TiAl alpha Ox micro/nanomaterial".CATALYSIS SCIENCE & TECHNOLOGY 5.2(2015):1041-1051. |
入库方式： OAI收割
来源：生态环境研究中心
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